Feeble Single-Atom Pd Catalysts for H2 Production from Formic Acid

E Doustkhah, N Tsunoji, S Mine, T Toyao… - … Applied Materials & …, 2024 - ACS Publications
Single-atom catalysts are thought to be the pinnacle of catalysis. However, for many
reactions, their suitability has yet to be unequivocally proven. Here, we demonstrate why …

Amine-functionalized hierarchically porous carbon supported Pd nanocatalysts for highly efficient H2 generation from formic acid with fast-diffusion channels

X Shao, X Miao, F Tian, M Bai, X Guo, W Wang… - Journal of Energy …, 2023 - Elsevier
Formic acid (FA) has come to be considered a potential candidate for hydrogen storage, and
the development of efficient catalysts for H 2 releasing is crucial for realizing the sustainable …

Ultrafine Pd Particles Embedded in Nitrogen-Enriched Mesoporous Carbon for Efficient H2 Production from Formic Acid Decomposition

J Sun, H Qiu, W Cao, H Fu, H Wan, Z Xu… - ACS Sustainable …, 2018 - ACS Publications
It remains a grand challenge to prepare highly efficient and stable Pd/C catalyst for catalytic
H2 production from formic acid (FA). Here through a simple deposition-precipitation method …

Mechanistic analysis-guided Pd-based catalysts for efficient hydrogen production from formic acid dehydrogenation

X Qin, H Li, S Xie, K Li, T Jiang, XY Ma, K Jiang… - ACS …, 2020 - ACS Publications
Heterogeneous catalysis of formic acid dehydrogenation at room temperature is a promising
tactic for safely storing and producing H2 as an efficient energy carrier. Up to now, the …

Pd Nanoalloys for H2 Generation from Formic Acid

E Doustkhah, M Hasani, Y Ide… - ACS Applied Nano …, 2019 - ACS Publications
Sourcing our ever-increasing demand for energy to power our high-paced and energy-
thirsty industries poses a never-ending challenge. Therefore, many academic, industrial …

Ultrasmall palladium nanoparticles supported on amine-functionalized SBA-15 efficiently catalyze hydrogen evolution from formic acid

K Koh, JE Seo, JH Lee, A Goswami… - Journal of Materials …, 2014 - pubs.rsc.org
The success of the so-called “hydrogen economy” for large-scale applications will ultimately
depend on efficient and sustainable production, storage and distribution of hydrogen. Owing …

Single Isolated Pd2+ Cations Supported on N-Doped Carbon as Active Sites for Hydrogen Production from Formic Acid Decomposition

DA Bulushev, M Zacharska, EV Shlyakhova… - ACS …, 2016 - ACS Publications
Single-site heterogeneous catalysis with isolated Pd atoms was reported earlier, mainly for
oxidation reactions and for Pd catalysts supported on oxide surfaces. In the present work, we …

Key Role of Anionic Doping for H2 Production from Formic Acid on Pd(111)

P Wang, SN Steinmann, G Fu, C Michel, P Sautet - ACS Catalysis, 2017 - ACS Publications
Hydrogen evolution by the catalytic decomposition of formic acid in solution is a key reaction
for hydrogen storage for which palladium is one of the most efficient catalysts. Based on …

Dehydrogenation of formic acid at room temperature: boosting palladium nanoparticle efficiency by coupling with pyridinic‐nitrogen‐doped carbon

QY Bi, JD Lin, YM Liu, HY He… - Angewandte Chemie …, 2016 - Wiley Online Library
The use of formic acid (FA) to produce molecular H2 is a promising means of efficient energy
storage in a fuel‐cell‐based hydrogen economy. To date, there has been a lack of …

Efficient H2 production from formic acid by a supported iron catalyst on silica

P Stathi, Y Deligiannakis, G Avgouropoulos… - Applied Catalysis A …, 2015 - Elsevier
Formic acid (FA) represents a convenient H 2-source/storage material. Herein, we introduce
two highly efficient heterogeneous catalysts for H 2-generation from FA, Fe II/RPPh 2@ SiO …