Design of biomaterials through direct ring-opening metathesis polymerisation of functionalised cyclic alkenes
S Kobayashi, M Tanaka - Molecular Systems Design & Engineering, 2023 - pubs.rsc.org
Ring-opening metathesis polymerisation (ROMP) has become a popular method for
synthesising complex functional polymers owing to the high functional group tolerance of …
synthesising complex functional polymers owing to the high functional group tolerance of …
Catalytic syntheses of degradable polymers via ring-opening metathesis copolymerization using vinyl ethers as chain transfer agents
Commercially available Vince lactam and its derivatives are copolymerized with 2, 3-
dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …
dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …
Catalytic Living Ring‐Opening Metathesis Polymerization Using Vinyl Ethers as Effective Chain‐Transfer Agents
A catalytic living ring‐opening metathesis copolymerization (ROMP) method is described
that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …
that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …
Polyethylene-grafted sheet-like silsesquioxane nanocomposites with unprecedented adhesion to polar substrates
Polyethylene is a highly apolar polymer with very poor adhesion to most substrates,
necessitating the use of tie layers. Therefore, the synthesis of functional polyethylene is a …
necessitating the use of tie layers. Therefore, the synthesis of functional polyethylene is a …
Advances in the synthesis of silyl-modified polymers (SMPs)
SM Guillaume - Polymer Chemistry, 2018 - pubs.rsc.org
Silyl-modified polymers (SMPs) are alkoxysilyl functionalized polymers of high importance
both academically and industrially. SMPs are being developed for coating, adhesive …
both academically and industrially. SMPs are being developed for coating, adhesive …
[HTML][HTML] Catalytic living ROMP: block copolymers from macro-chain transfer agents
A Mandal, AFM Kilbinger - Polymer Chemistry, 2023 - pubs.rsc.org
Vinyl ether based macro-chain transfer agents (m-CTAs) are used to produce different di or
tri-block copolymers under catalytic living ROMP conditions. Polystyrene (PS) vinyl ether m …
tri-block copolymers under catalytic living ROMP conditions. Polystyrene (PS) vinyl ether m …
Polythiourethanes crosslinked with dynamic disulfide bonds: Synthesis via nonisocyanate approach, thermomechanical and reprocessing properties
W Ge, B Zhao, W Liu, K Nie… - Macromolecular Rapid …, 2021 - Wiley Online Library
Polythiourethanes (PTUs) crosslinked with dynamic disulfide bonds are synthesized via a
nonisocyanate approach. First, a difunctional five‐membered cyclic trithiocarbonate (1) is …
nonisocyanate approach. First, a difunctional five‐membered cyclic trithiocarbonate (1) is …
Pulsed-Addition ROMP: Catalytic Syntheses of Heterotelechelic Polymers via Regioselective Chain Transfer Agents
Regioselective chain transfer agents are used to synthesize narrowly dispersed
heterotelechelic polymers with a 15-fold decrease in catalyst consumption using the pulsed …
heterotelechelic polymers with a 15-fold decrease in catalyst consumption using the pulsed …
High-performance nonisocyanate thermoplastic polythiourethane with high hydrogen bond content
B Xu, Q Yin, C Su, J Cheng, J Zhang, J Zhao - ACS Macro Letters, 2022 - ACS Publications
Nonisocyanate polyurethane (NIPU) has been extensively studied because of its
sustainability potential. However, the low reactivity of five-membered cyclocarbonates with …
sustainability potential. However, the low reactivity of five-membered cyclocarbonates with …
Regioselective cross metathesis for block and heterotelechelic polymer synthesis
Ring-opening metathesis polymerization (ROMP) of 3-substituted cyclooctene (3RCOE)
monomers with Grubbs 2nd and 3rd generation catalysts (G2 and G3) has been shown to …
monomers with Grubbs 2nd and 3rd generation catalysts (G2 and G3) has been shown to …