Design of biomaterials through direct ring-opening metathesis polymerisation of functionalised cyclic alkenes

S Kobayashi, M Tanaka - Molecular Systems Design & Engineering, 2023 - pubs.rsc.org
Ring-opening metathesis polymerisation (ROMP) has become a popular method for
synthesising complex functional polymers owing to the high functional group tolerance of …

Catalytic syntheses of degradable polymers via ring-opening metathesis copolymerization using vinyl ethers as chain transfer agents

A Mandal, I Mandal, AFM Kilbinger - Macromolecules, 2022 - ACS Publications
Commercially available Vince lactam and its derivatives are copolymerized with 2, 3-
dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …

Catalytic Living Ring‐Opening Metathesis Polymerization Using Vinyl Ethers as Effective Chain‐Transfer Agents

A Mandal, I Mandal… - Angewandte Chemie …, 2023 - Wiley Online Library
A catalytic living ring‐opening metathesis copolymerization (ROMP) method is described
that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …

Polyethylene-grafted sheet-like silsesquioxane nanocomposites with unprecedented adhesion to polar substrates

V Sharma, U Paulbudhe, N Bachhar… - ACS Applied Polymer …, 2023 - ACS Publications
Polyethylene is a highly apolar polymer with very poor adhesion to most substrates,
necessitating the use of tie layers. Therefore, the synthesis of functional polyethylene is a …

Advances in the synthesis of silyl-modified polymers (SMPs)

SM Guillaume - Polymer Chemistry, 2018 - pubs.rsc.org
Silyl-modified polymers (SMPs) are alkoxysilyl functionalized polymers of high importance
both academically and industrially. SMPs are being developed for coating, adhesive …

[HTML][HTML] Catalytic living ROMP: block copolymers from macro-chain transfer agents

A Mandal, AFM Kilbinger - Polymer Chemistry, 2023 - pubs.rsc.org
Vinyl ether based macro-chain transfer agents (m-CTAs) are used to produce different di or
tri-block copolymers under catalytic living ROMP conditions. Polystyrene (PS) vinyl ether m …

Polythiourethanes crosslinked with dynamic disulfide bonds: Synthesis via nonisocyanate approach, thermomechanical and reprocessing properties

W Ge, B Zhao, W Liu, K Nie… - Macromolecular Rapid …, 2021 - Wiley Online Library
Polythiourethanes (PTUs) crosslinked with dynamic disulfide bonds are synthesized via a
nonisocyanate approach. First, a difunctional five‐membered cyclic trithiocarbonate (1) is …

Pulsed-Addition ROMP: Catalytic Syntheses of Heterotelechelic Polymers via Regioselective Chain Transfer Agents

A Mandal, I Mandal, AFM Kilbinger - ACS Macro Letters, 2022 - ACS Publications
Regioselective chain transfer agents are used to synthesize narrowly dispersed
heterotelechelic polymers with a 15-fold decrease in catalyst consumption using the pulsed …

High-performance nonisocyanate thermoplastic polythiourethane with high hydrogen bond content

B Xu, Q Yin, C Su, J Cheng, J Zhang, J Zhao - ACS Macro Letters, 2022 - ACS Publications
Nonisocyanate polyurethane (NIPU) has been extensively studied because of its
sustainability potential. However, the low reactivity of five-membered cyclocarbonates with …

Regioselective cross metathesis for block and heterotelechelic polymer synthesis

MR Radlauer, ME Matta, MA Hillmyer - Polymer Chemistry, 2016 - pubs.rsc.org
Ring-opening metathesis polymerization (ROMP) of 3-substituted cyclooctene (3RCOE)
monomers with Grubbs 2nd and 3rd generation catalysts (G2 and G3) has been shown to …