Diterpenoids of terrestrial origin

JR Hanson - Natural product reports, 2015 - pubs.rsc.org
Covering: January to December 2013. Previous review, Nat. Prod. Rep., 2013, 30, 1346–
1356 This review covers the isolation and chemistry of diterpenoids from terrestrial as …

Asymmetric Divergent Synthesis of ent-Kaurane-, ent-Atisane-, ent-Beyerane-, ent-Trachylobane-, and ent-Gibberellane-type Diterpenoids

XH Zhao, LL Meng, XT Liu, PF Shu… - Journal of the …, 2022 - ACS Publications
A unified strategy toward asymmetric divergent syntheses of nine C8-ethano-bridged
diterpenoids A1–A9 (candol A, powerol, sicanadiol, epi-candol A, atisirene, ent-atisan-16α …

Total Synthesis of Atisane-Type Diterpenoids: Application of Diels–Alder Cycloadditions of Podocarpane-Type Unmasked ortho-Benzoquinones

L Song, G Zhu, Y Liu, B Liu, S Qin - Journal of the American …, 2015 - ACS Publications
Few examples of [4+ 2] cycloaddition with unmasked ortho-benzoquinones (UMOBs) as
carbodiene have been reported in complex molecule synthesis. Herein we report that this …

Divergent Total Synthesis of Euphoranginol C, Euphoranginone D, ent‐Trachyloban‐3β‐ol, ent‐Trachyloban‐3‐one, Excoecarin E, and ent‐16α‐Hydroxy …

ZJ Xu, Y Zong, YN Qiao, JZ Zhang, X Liu… - Angewandte Chemie …, 2020 - Wiley Online Library
A divergent synthetic approach to biogenetically related diterpenoids such as ent‐kauranes,
ent‐trachylobanes, ent‐beyerane, and ent‐atisane has been developed. The unified …

The effect of isolates from Cassipourea flanaganii (Schinz) alston, a plant used as a skin lightning agent, on melanin production and tyrosinase inhibition

MK Langat, NC Dlova, LE Mulcahy-Ryan… - Journal of …, 2021 - Elsevier
Abstract Ethnopharmacological relevance The Zulu and Xhosa people of South Africa use
the stem bark of Cassipourea flanaganii as a skin-lightning cosmetic. Aim of the study To …

Total synthesis of stemarene and betaerene diterpenoids: Divergent ring-formation strategy and late-stage C–H functionalization

R Chen, F Zhang, Y Hua, D Shi, X Lei, H Xiao… - CCS …, 2022 - chinesechemsoc.org
A unified protecting group-free approach to two stemarene and two betaerene diterpenoids
through a bioinspired two-phase strategy has been developed, and three of them were …

Forwards and backwards–synthesis of Laurencia natural products using a biomimetic and retrobiomimetic strategy incorporating structural reassignment of …

HSS Chan, AL Thompson, KE Christensen… - Chemical …, 2020 - pubs.rsc.org
Laurefurenynes C–F are four natural products isolated from Laurencia species whose
structures were originally determined on the basis of extensive nuclear magnetic resonance …

[PDF][PDF] Synthetic transformations of ent-kaurenoic acid

MC Olga - Chemistry Journal of Moldova, 2015 - ibn.idsi.md
This paper presents a review on kaurane diterpenes, covering various aspects of chemical
and microbiological transformations of native ent-kaurenoic acid, namely, its reactions via …

Viability of Nonclassical Carbocations Proposed as Intermediates in the Biosynthesis of Atiserene, Beyerene, Kaurene, and Trachylobane Diterpenes

YJ Hong, DJ Tantillo - Helvetica Chimica Acta, 2014 - Wiley Online Library
The results of quantum‐chemical calculations aimed at assessing the viability of
nonclassical carbocations proposed to be involved in the biosynthesis of atiserne, beyerene …

Acrocalyenes A and B, Two New Diterpenoids from Sinomenium acutum Associated Fungus Acrocalymma sp.

J Liu, T Yang, YH Yuan, JY Hu, LB Lin… - Chemistry & …, 2022 - Wiley Online Library
We identified two new diterpenoidal acrocalyenes A (1) and B (2) through chemical
investigation on Acrocalymma sp., a plant‐associated fungus from the tender stem isolates …