Chiral pesticides: identification, description, and environmental implications

EM Ulrich, CN Morrison, MR Goldsmith… - … and Toxicology Volume …, 2012 - Springer
Anthropogenic chemicals, including pesticides, are a major source of contamination and
pollution in the environment. Pesticides have many positive uses: increased food …

Chirality of pollutants—effects on metabolism and fate

TA Müller, HPE Kohler - Applied microbiology and biotechnology, 2004 - Springer
In most cases, enantiomers of chiral compounds behave differently in biochemical
processes. Therefore, the effects and the environmental fate of the enantiomers of chiral …

Complete microbial degradation of both enantiomers of the chiral herbicide mecoprop [(RS)-2-(4-chloro-2-methylphenoxy) propionic acid] in an enantioselective …

C Zipper, K Nickel, W Angst… - Applied and …, 1996 - Am Soc Microbiol
Sphingomonas herbicidovorans MH (previously designated Flavobacterium sp. strain MH)
was able to utilize the chiral herbicide (RS)-2-(4-chloro-2-methylphenoxy) propionic acid …

Commonly used chiral drugs: a survey

JS Millership, A Fitzpatrick - Chirality, 1993 - Wiley Online Library
Initial results of a comparative survey of commonly used chiral drugs are presented. The
survey considered the differences between drugs used in 1982 with those in use in 1991 …

Involvement of two alpha-ketoglutarate-dependent dioxygenases in enantioselective degradation of (R)-and (S)-mecoprop by Sphingomonas herbicidovorans MH

K Nickel, MJF Suter, HP Kohler - Journal of bacteriology, 1997 - Am Soc Microbiol
Cell extracts of Sphingomonas herbicidovorans MH grown on (R)-mecoprop contained an
enzyme activity that selectively converted (R)-mecoprop to 4-chloro-2-methylphenol …

Plant and soil enantioselective biodegradation of racemic phenoxyalkanoic herbicides

JM Schneiderheinze, DW Armstrong… - Chirality: The …, 1999 - Wiley Online Library
The biodegradation of the chiral phenoxyalkanoic herbicides 2‐(2, 4‐dichlorophenoxy)
propionic aid (2, 4‐DP) and 2‐(4‐chloro‐2‐methylphenoxy) propionic acid (MCPP) was …

Fate of the herbicides mecoprop, dichlorprop, and 2, 4-D in aerobic and anaerobic sewage sludge as determined by laboratory batch studies and enantiomer-specific …

C Zipper, C Bolliger, T Fleischmann, MJF Suter… - Biodegradation, 1999 - Springer
Aerobic degradation experiments with the racemic mixtures of mecoprop and dichlorprop
revealed that activated sludge collected from the aeration tank of a municipal waste water …

Relevance of enantiomeric separations in environmental science

DW Armstrong, GL Reid Iii, ML Hilton, CD Chang - Environmental pollution, 1993 - Elsevier
A significant number of all organic chemicals that are released into the environment are
racemic mixtures. Most environmental regulations and scientific environmental studies treat …

Sphingomonas herbicidovorans MH: a versatile phenoxyalkanoic acid herbicide degrader

HPE Kohler - Journal of Industrial Microbiology and …, 1999 - academic.oup.com
Sphingomonas herbicidovorans MH was isolated from a dichlorprop-degrading soil column.
It is able to grow on phenoxyalkanoic acid herbicides, such as mecoprop, dichlorprop, 2, 4 …

Stereoselective degradation kinetics of tebuconazole in rabbits

W Zhu, J Qiu, Z Dang, C Lv, G Jia, L Li… - Chirality: The …, 2007 - Wiley Online Library
Abstract Tebuconazole [(RS)‐1‐p‐chlorophenyl‐4, 4‐dimethyl‐3‐(1H‐1, 2, 4‐triazol‐1‐
ylmethyl) pentan‐3‐ol] is a potent triazole fungicide and consists of a pair of enantiomers …