Thermolysis of coenzymes B12 at physiological temperatures: activation parameters for cobalt–carbon bond homolysis and a quantitative analysis of the perturbation …

KL Brown, X Zou - Journal of Inorganic Biochemistry, 1999 - Elsevier
The kinetics of the thermolysis of 5′-deoxyadenosylcobalamin (AdoCbl, coenzyme B12) in
aqueous solution, pH 7.5, have been studied in the temperature range 30–85° C using …

4'-5'-Unsaturated 5'-halogenated nucleosides. Mechanism-based and competitive inhibitors of S-adenosyl-L-homocysteine hydrolase

ET Jarvi, JR McCarthy, S Mehdi… - Journal of medicinal …, 1991 - ACS Publications
Palmer and Abeles7® reported that 4,, 5,-didehydro-5'-deoxyadenosine (5) is converted to
both adenosine and SAH by SAH hydrolase, presumably via ketone 2. This observation led …

Synthesis and properties of purine nucleosides and nucleotides

PC Srivastava, RK Robins, RB Meyer Jr - Chemistry of Nucleosides and …, 1988 - Springer
Inosinic acid was the first nucleotide obtained from nature and was reported by von Liebig in
1847. This was followed by the isolation of the first nucleoside, guanosine, by E. Schulze …

Isolation, Stereochemistry, and Configurational Lability of Optically Active Telluroxides

T Shimizu, Y Yamazaki, H Taka… - Journal of the American …, 1997 - ACS Publications
Ever since an optically active enantiomeric selenoxide was obtained for the first time by
Davis and co-workers in 1983, 1, 2 there have been several reports on the isolation of …

Optical resolution and racemization of areneseleninic acids

T Shimizu, Y Nakashima, I Watanabe… - Journal of the …, 2002 - pubs.rsc.org
Various optically active areneseleninic acids (ArSeO2H; Ar= 4-Me-C6H4; 4-MeO-C6H4; 2-
MeO-C6H4; 2-MeOCO-C6H4; 2, 4, 6-Me3-C6H2; 2, 4, 6-Et3-C6H2; 2, 4, 6-iPr3-C6H2; 2, 4, 6 …

Pyridylseleno group in organic synthesis. Part 4. Oxyseleniation of olefins using pyridine-2-selenenyl bromide as a selenium reagent and its utilization in the synthesis …

A Toshimitsu, H Owada, K Terao, S Uemura… - Journal of the Chemical …, 1985 - pubs.rsc.org
The reaction of olefins with pyridine-2-selenenyl bromide in methanol as solvent affords β-
methoxyalkyl 2-pyridyl selenides (A) in good to excellent yields. This reaction also proceeds …

[PDF][PDF] Selectivity in Selenoxide and Telluroxide Eliminations as Double Bond Forming Reactions (Commemoration Issue Dedicated to Professor Masaya Okano on …

S Uemura, A Toshimitsu - Bulletin of the Institute for …, 1984 - repository.kulib.kyoto-u.ac.jp
the sole product when Y= OH, OR, OAc, and NHCOCH3, while a vinylic compound [\C=--C
(Y)—C—] was the main or the sole product when Y= CN, COR, CO2R, C= C, CC, NCS, NO2 …

Synthesis and stereochemistry of optically active selenium and tellurium compounds

N Kamigata - Phosphorus, Sulfur, and Silicon and the Related …, 2005 - Taylor & Francis
The synthesis and stereochemistry of tricoordinated optically active selenium and tellurium
compounds are described. Telluronium salts, telluronium imides, and seleninic acids were …

Optical resolution of selenonium imides stabilized by an 8-dimethylamino-1-naphthyl group

T Soma, N Kamigata, K Hirabayashi… - Bulletin of the …, 2007 - academic.oup.com
Selenonium imides 1 and 2, stabilized by intramolecular coordination of the amino group of
8-dimethylamino-1-naphthyl substituent to the selenium atom, were synthesized. Optically …

Synthesis and stereochemistry of optically active organic selenium and tellurium compounds

T Shimizu, N Kamigata - Journal of Synthetic Organic Chemistry …, 1997 - jstage.jst.go.jp
Some optically active tricoordinate selenium and tellurium compounds, such as selenonium
ylide, telluronium ylide, selenonium imide, selenonium salt, telluronium salt, and telluroxide …