With the rapid development of asymmetric catalysis, the demand for the enantioselective
synthesis of complex and diverse molecules with different chiral elements is increasing …

Heterocyclic chemistry is an ever-expanding field without boundaries. Heterocycles play a
significant role in medicinal and pharmaceutical chemistry, the agricultural industry and …

Axially chiral N‐substituted quinazolinones are important bioactive molecules, which are
presented in many synthetic drugs. However, most strategies toward their atroposelective …

The first atroposelective desymmetrization of prochiral N-aryl maleimides through its
conversion to axially chiral phthalimides is developed by applying a de novo arene …

We describe herein an intriguing method for the synthesis of biaryl aldehydes bearing both
axial and central chirality through a desymmetric [3+ 2] cycloaddition reaction of activated …

Herein, a new strategy for the enantioselective synthesis of axially chiral N-aryl succinimides
was devised by [3+ 2] annulation of MBH carbonates and N-aryl maleimides under chiral …

The development of efficient processes for the preparation of structurally diverse axially
chiral biaryls has been an important goal in synthetic organic chemistry and asymmetric …

In recent years, the silver‐catalyzed and silver‐promoted isocyanide reactions have
attracted much attention, due to its efficiency in the formation of diverse new bonds and good …

Herein, we report an l-valine-derived amide phosphine-catalyzed [3+ 2] cyclization of MBH
carbonates and N-(2-tert-butylphenyl) maleimides via asymmetric desymmetrization. Bicyclic …

Atropisomers possessing additional stereogenic centres have found wide applications in
various fields; however, the development of catalytic asymmetric reactions for their …