Reactions in single-molecule junctions

H Chen, C Jia, X Zhu, C Yang, X Guo… - Nature Reviews …, 2023 - nature.com
Developing new materials is a long-standing goal that extends across the fields of synthesis,
catalysis, nanotechnology and materials science. Transforming one compound or material …

On-surface synthesis toward two-dimensional polymers

T Niu, C Hua, M Zhou - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
Two-dimensional (2D) polymers have garnered widespread interest because of their
intriguing physicochemical properties. Envisaged applications in fields including …

Electron-catalyzed dehydrogenation in a single-molecule junction

H Chen, F Jiang, C Hu, Y Jiao, S Chen… - Journal of the …, 2021 - ACS Publications
Investigating how electrons propagate through a single molecule is one of the missions of
molecular electronics. Electrons, however, are also efficient catalysts for conducting radical …

Noncontact atomic force microscopy: Bond imaging and beyond

Q Zhong, X Li, H Zhang, L Chi - Surface Science Reports, 2020 - Elsevier
It was a long-cherished dream for chemists to take a direct look at chemical bonding, a
fundamental component of chemistry. This dream was finally accomplished by the state-of …

In situ monitoring of transmetallation in electric potential-promoted oxidative coupling in a single-molecule junction

Y Li, C Zhao, R Wang, A Tang, W Hong, D Qu… - CCS …, 2023 - chinesechemsoc.org
To monitor and investigate chemical reactions in real time and in situ is a long-standing,
challenging goal in chemistry. Herein, an electric potential-promoted oxidative coupling …

Nanoscale surface modification via scanning electrochemical probe microscopy

E Oswald, K Palanisamy, C Kranz - Current Opinion in Electrochemistry, 2022 - Elsevier
Micro-and nanoscale surface modification using scanning probe microscopy techniques in
combination with electrochemically induced surface structuring provides a maskless in situ …

Intramolecular coupling of terminal alkynes by atom manipulation

F Albrecht, D Rey, S Fatayer, F Schulz… - Angewandte …, 2020 - Wiley Online Library
Glaser‐like coupling of terminal alkynes by thermal activation is extensively used in on‐
surface chemistry. Here we demonstrate an intramolecular version of this reaction performed …

Innovations in nanosynthesis: emerging techniques for precision, scalability, and spatial control in reactions of organic molecules on solid surfaces

J Lipton-Duffin, J MacLeod - Journal of Physics: Condensed …, 2023 - iopscience.iop.org
The surface science-based approach to synthesising new organic materials on surfaces has
gained considerable attention in recent years, owing to its success in facilitating the …

Real-time imaging of on-surface Ullmann polymerization reveals an inhibiting effect of adatoms

D Dettmann, M Panighel… - Journal of the …, 2024 - ACS Publications
Ullmann coupling is a widely used reaction for the on-surface growth of low-dimensional
carbon nanomaterials. The irreversible nature of this reaction prevents the “self-healing” of …

Deciphering the Mechanism of On-Surface Dehydrogenative C–C Coupling Reactions

Q Zhong, J Jung, D Kohrs, LA Kaczmarek… - Journal of the …, 2024 - ACS Publications
On-surface synthesis has proven to be a powerful approach for fabricating various low-
dimensional covalent nanostructures with atomic precision that could be challenging for …