Luminescence and Length Control in Nonchelated d8‐Metallosupramolecular Polymers through Metal‐Metal Interactions

J Matern, I Maisuls, CA Strassert… - Angewandte Chemie …, 2022 - Wiley Online Library
Supramolecular polymers (SPs) of d8 transition metal complexes have received
considerable attention by virtue of their rich photophysical properties arising from metal …

Impact of positional isomerism on pathway complexity in aqueous media

I Helmers, B Shen, KK Kartha… - Angewandte Chemie …, 2020 - Wiley Online Library
Pathway complexity has become an important topic in recent years due to its relevance in
the optimization of molecular assembly processes, which typically require precise sample …

Supramolecular polymer bottlebrushes

FV Gruschwitz, T Klein, S Catrouillet… - Chemical …, 2020 - pubs.rsc.org
The field of supramolecular chemistry has long been known to generate complex materials
of different sizes and shapes via the self-assembly of single or multiple low molar mass …

MXene‐Polymer Hybrid for High‐Performance Gas Sensor Prepared by Microwave‐Assisted In‐Situ Intercalation

J Zhou, SH Hosseini Shokouh… - Advanced Materials …, 2022 - Wiley Online Library
Abstract 2D transition‐metal carbides (Ti3C2Tx MXene) intercalated with organic molecules
have been widely used in batteries and supercapacitors, but are quite rarely reported for gas …

Supramolecular biomaterials in the Netherlands

MB Baker, AW Bosman, MAJ Cox… - … Engineering Part A, 2022 - liebertpub.com
Synthetically designed biomaterials strive to recapitulate and mimic the complex
environment of natural systems. Using natural materials as a guide, the ability to create high …

Squaramide‐Based Supramolecular Materials Drive HepG2 Spheroid Differentiation

T Liu, L van den Berk, JAJ Wondergem… - Advanced …, 2021 - Wiley Online Library
A major challenge in the use of HepG2 cell culture models for drug toxicity screening is their
lack of maturity in 2D culture. 3D culture in Matrigel promotes the formation of spheroids that …

Spatial and temporal modulation of cell instructive cues in a filamentous supramolecular biomaterial

C Tong, JAJ Wondergem, M van den Brink… - … applied materials & …, 2022 - ACS Publications
Supramolecular materials provide unique opportunities to mimic both the structure and
mechanics of the biopolymer networks that compose the extracellular matrix. However …

Hydrophobic domain flexibility enables morphology control of amphiphilic systems in aqueous media

I Helmers, N Bäumer, G Fernández - Chemical Communications, 2020 - pubs.rsc.org
Herein, we introduce the concept of hydrophobic domain flexibility to control the morphology
of aqueous assemblies. To this end, we examined two amphiphilic 4, 4-difluoro-4-bora-3a …

Self-assembly of amphiphilic aryl-squaramides in water driven by dipolar π–π interactions

S Bujosa, E Castellanos, A Frontera… - Organic & …, 2020 - pubs.rsc.org
Squaramides are versatile compounds with a great capacity to interact via non-covalent
interactions and therefore of interest for the development of supramolecular systems and …

[HTML][HTML] Morphology control in metallosupramolecular assemblies through solvent-induced steric demand

N Bäumer, KK Kartha, JP Palakkal, G Fernández - Soft Matter, 2020 - pubs.rsc.org
Controlling the supramolecular self-assembly of π-conjugated systems into defined
morphologies is a prerequisite for the preparation of functional materials. In recent years, the …