Paramagnetic chemical probes have been used in electron paramagnetic resonance (EPR)
and nuclear magnetic resonance (NMR) spectroscopy for more than four decades. Recent …

EPR spectroscopy is an increasingly useful analytical tool to probe biomolecule structure,
dynamic behaviour, and interactions. Nitroxide radicals are the most commonly used radical …

The study of ever more complex biomolecular assemblies implicated in human health and
disease is facilitated by a suite of complementary biophysical methods. Pulse dipolar …

Pulse-dipolar EPR is an appealing strategy for structural characterization of complex
systems in solution that complements other biophysical techniques. Significantly, the …

Electron paramagnetic resonance (EPR) distance measurements are making increasingly
important contributions to studies of biomolecules underpinning health and disease by …

Pulse dipolar EPR spectroscopy (PDS) measurements are an important complementary tool
in structural biology and are increasingly applied to macromolecular assemblies implicated …

Biomolecular applications of pulse dipolar electron paramagnetic resonance spectroscopy
(PDS) are becoming increasingly valuable in structural biology. Site-directed spin labelling …

We present herein a novel nitroxide spin label‐containing RNA triphosphate TPT3NO and
its application for site‐specific spin‐labeling of RNA through in vitro transcription using an …

Oxidative C–O coupling of pyrazolones with N-hydroxy compounds of different classes (N-
hydroxyphthalimide, N-hydroxybenzotriazole, oximes) was achieved; both one-electron …

The field of free-radical reagents in organic chemistry has been associated with aminoxyl
radicals (mainly TEMPO and its analogues) for a long time. Diacetyliminoxyl is the first …