Programming mechanical properties through encoded network topologies

BR Clarke, GN Tew - Journal of Polymer Science, 2024 - Wiley Online Library
Polymer networks remain an essential class of soft materials. Despite their use in everyday
materials, connecting the molecular structure of the network to its macroscopic properties …

Click chemistry in polymer science

R Hoogenboom - Chem, 2023 - cell.com
The concept of click chemistry has revolutionized chemical sciences. For polymer science,
these high-efficiency coupling reactions are of great importance because they enable …

Topology Matters: Conformation and Microscopic Dynamics of Ring Polymers

M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …

Ancillary Ligand Lability Improves Control in Cyclic Ruthenium Benzylidene Initiated Ring-Expansion Metathesis Polymerizations

AM Levenson, CM Morrison, PR Huang… - ACS Macro …, 2023 - ACS Publications
The synthesis of well-defined cyclic polymers is crucial to exploring applications spanning
engineering, energy, and biomedicine. These materials lack chain-ends and are therefore …

Design of Topology‐Controlled Polyethers toward Robust Cooperative Hydrogen Bonding

J Kim, S Choi, J Baek, YI Park, JC Kim… - Advanced Functional …, 2023 - Wiley Online Library
Topology control of polymers is critical for determining their physical properties and potential
applications; in particular, topologies that incorporate numerous hydrogen bonding (H …

Kinetics of heterogeneous polymerization of glycidol with B (C6F5) 3 in toluene in the absence and presence of water

EG Urreizti, X Gastearena, A Lam… - Materials Today …, 2024 - Elsevier
The synthesis of polyglycidol (or polyglycerol) using tris-(pentafluorophenyl) borane [B (C 6
F 5) 3] as a catalyst produces a branched structure with a cyclic core by a mechanism of …

[HTML][HTML] E-Polymers: Applications in Biological Interfaces and Organisms

W Dou, S Wang, R Yang - Nanoenergy Advances, 2023 - mdpi.com
Future electronics will play a more critical role in people's lives, as reflected in the realization
of advanced human–machine interfaces, disease detection, medical treatment, and health …

Facile synthesis of cyclic RAFT agents and ring expansion radical polymerization of vinyl monomers having cyclic topology

H Ito, K Oto, A Takasu, M Higuchi - Polymer Chemistry, 2024 - pubs.rsc.org
In this paper, we describe the synthesis of cyclic vinyl polymers by ring-expansion radical
polymerization using a cyclic RAFT agent, which is prepared by bimolecular ring-closing …

Enabling Closed‐Loop Circularity of “Non‐Polymerizable” α, β‐Conjugated Lactone Towards High‐Performance Polyester with the Assistance of Cyclopentadiene

XT Wu, C Yang, JS Xi, C Shi, FS Du… - Angewandte Chemie …, 2024 - Wiley Online Library
Chemical recycling of polymers to monomers presents a promising solution to the escalating
crisis associated with plastic waste. Despite considerable progress made in this field, the …

Synthesis and Characterization of a Luminescent Cyclic Poly (ethylene oxide)–Polypyridyl Ruthenium Complex

MA Aboudzadeh, V Rodríguez-Fanjul… - ACS Macro …, 2023 - ACS Publications
We report the synthesis of a macrocyclic poly (ethylene oxide)(PEO) connected by one [Ru
(bpy) 3] 2+ unit (where bpy= 2, 2′-bipyridine), a photoactive metal complex that provides …