Programming mechanical properties through encoded network topologies
Polymer networks remain an essential class of soft materials. Despite their use in everyday
materials, connecting the molecular structure of the network to its macroscopic properties …
materials, connecting the molecular structure of the network to its macroscopic properties …
Click chemistry in polymer science
R Hoogenboom - Chem, 2023 - cell.com
The concept of click chemistry has revolutionized chemical sciences. For polymer science,
these high-efficiency coupling reactions are of great importance because they enable …
these high-efficiency coupling reactions are of great importance because they enable …
Topology Matters: Conformation and Microscopic Dynamics of Ring Polymers
M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …
simplest polymer without ends, giving rise to important topology related properties. We …
Ancillary Ligand Lability Improves Control in Cyclic Ruthenium Benzylidene Initiated Ring-Expansion Metathesis Polymerizations
AM Levenson, CM Morrison, PR Huang… - ACS Macro …, 2023 - ACS Publications
The synthesis of well-defined cyclic polymers is crucial to exploring applications spanning
engineering, energy, and biomedicine. These materials lack chain-ends and are therefore …
engineering, energy, and biomedicine. These materials lack chain-ends and are therefore …
Design of Topology‐Controlled Polyethers toward Robust Cooperative Hydrogen Bonding
J Kim, S Choi, J Baek, YI Park, JC Kim… - Advanced Functional …, 2023 - Wiley Online Library
Topology control of polymers is critical for determining their physical properties and potential
applications; in particular, topologies that incorporate numerous hydrogen bonding (H …
applications; in particular, topologies that incorporate numerous hydrogen bonding (H …
Kinetics of heterogeneous polymerization of glycidol with B (C6F5) 3 in toluene in the absence and presence of water
EG Urreizti, X Gastearena, A Lam… - Materials Today …, 2024 - Elsevier
The synthesis of polyglycidol (or polyglycerol) using tris-(pentafluorophenyl) borane [B (C 6
F 5) 3] as a catalyst produces a branched structure with a cyclic core by a mechanism of …
F 5) 3] as a catalyst produces a branched structure with a cyclic core by a mechanism of …
[HTML][HTML] E-Polymers: Applications in Biological Interfaces and Organisms
W Dou, S Wang, R Yang - Nanoenergy Advances, 2023 - mdpi.com
Future electronics will play a more critical role in people's lives, as reflected in the realization
of advanced human–machine interfaces, disease detection, medical treatment, and health …
of advanced human–machine interfaces, disease detection, medical treatment, and health …
Facile synthesis of cyclic RAFT agents and ring expansion radical polymerization of vinyl monomers having cyclic topology
H Ito, K Oto, A Takasu, M Higuchi - Polymer Chemistry, 2024 - pubs.rsc.org
In this paper, we describe the synthesis of cyclic vinyl polymers by ring-expansion radical
polymerization using a cyclic RAFT agent, which is prepared by bimolecular ring-closing …
polymerization using a cyclic RAFT agent, which is prepared by bimolecular ring-closing …
Enabling Closed‐Loop Circularity of “Non‐Polymerizable” α, β‐Conjugated Lactone Towards High‐Performance Polyester with the Assistance of Cyclopentadiene
XT Wu, C Yang, JS Xi, C Shi, FS Du… - Angewandte Chemie …, 2024 - Wiley Online Library
Chemical recycling of polymers to monomers presents a promising solution to the escalating
crisis associated with plastic waste. Despite considerable progress made in this field, the …
crisis associated with plastic waste. Despite considerable progress made in this field, the …
Synthesis and Characterization of a Luminescent Cyclic Poly (ethylene oxide)–Polypyridyl Ruthenium Complex
MA Aboudzadeh, V Rodríguez-Fanjul… - ACS Macro …, 2023 - ACS Publications
We report the synthesis of a macrocyclic poly (ethylene oxide)(PEO) connected by one [Ru
(bpy) 3] 2+ unit (where bpy= 2, 2′-bipyridine), a photoactive metal complex that provides …
(bpy) 3] 2+ unit (where bpy= 2, 2′-bipyridine), a photoactive metal complex that provides …