Stereoselective chemical 1, 2-cis O-glycosylation: from 'sugar ray'to modern techniques of the 21st century

AV Demchenko - Synlett, 2003 - thieme-connect.com
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N-trichloroethoxycarbonyl-glucosamine derivatives as glycosyl donors

W Dullenkopf, JC Castro-Palomino, L Manzoni… - Carbohydrate …, 1996 - Elsevier
d-Glucosamine can be readily transformed into 1, 3, 4, 6-tetra-O-acetyl-2-deoxy-2-(2, 2, 2-
trichloroethoxycarbonylamino)-d-glucopyranose (2). From this intermediate valuable …

Synthesis of the docosanasaccharide arabinan domain of mycobacterial arabinogalactan and a proposed octadecasaccharide biosynthetic precursor

M Joe, Y Bai, RC Nacario… - Journal of the American …, 2007 - ACS Publications
Two major components of the cell wall in mycobacteria, including Mycobacterium
tuberculosis, the causative agent of tuberculosis (TB), are polysaccharides containing …

Total synthesis of Lentinus giganteus glycans with antitumor activities via stereoselective α-glycosylation and orthogonal one-pot glycosylation strategies

Y Zhang, Y Hu, S Liu, H He, R Sun, G Lu, G Xiao - Chemical Science, 2022 - pubs.rsc.org
The accessibility to long, branched and complex glycans containing many 1, 2-cis glycosidic
linkages with precise structures remains a challenging task in chemical synthesis. Reported …

Synthesis of docosasaccharide arabinan motif of mycobacterial cell wall

A Ishiwata, Y Ito - Journal of the American Chemical Society, 2011 - ACS Publications
Mycobacterial arabinan is a common constituent of both arabinogalactan (AG) and
lipoarabinomannan (LAM). In this study, synthesis of β-Ara f containing common arabinan …

Pushing the limits of automated glycan assembly: synthesis of a 50mer polymannoside

K Naresh, F Schumacher, HS Hahm… - Chemical …, 2017 - pubs.rsc.org
Automated glycan assembly (AGA) enables rapid access to oligosaccharides. The overall
length of polymers created via automated solid phase synthesis depends on very high yields …

Progress and challenges in the synthesis of sequence controlled polysaccharides

G Fittolani, T Tyrikos-Ergas, D Vargová… - Beilstein Journal of …, 2021 - beilstein-journals.org
The sequence, length and substitution of a polysaccharide influence its physical and
biological properties. Thus, sequence controlled polysaccharides are important targets to …

Twenty years of mycobacterial glycans: furanosides and beyond

TL Lowary - Accounts of chemical research, 2016 - ACS Publications
Conspectus The cell surface (or cell wall) of bacteria is coated with carbohydrate (or glycan)
structures that play a number of important roles. These include providing structural integrity …

Highly efficient chemoenzymatic synthesis of α-galactosyl epitopes with a recombinant α (1→ 3)-galactosyltransferase

J Fang, J Li, X Chen, Y Zhang, J Wang… - Journal of the …, 1998 - ACS Publications
α-Galactosyl epitopes are carbohydrate structures bearing a Galα1-3Galβ terminus. The
interaction of these epitopes on the surface of animal cells with anti-α-galactosyl antibodies …

Total Synthesis of Cordyceps militaris Glycans via Stereoselective Orthogonal One-Pot Glycosylation and α-Glycosylation Strategies

Y Ma, Q Jiang, X Wang, G Xiao - Organic Letters, 2022 - ACS Publications
Cordyceps militaris glycans with potent antioxidant activities have been efficiently and
collectively synthesized. The synthetic approach features the following:(1) a stereoselective …