[HTML][HTML] Magnetic molecules on surfaces: SMMs and beyond

G Gabarró-Riera, G Aromí, EC Sañudo - Coordination Chemistry Reviews, 2023 - Elsevier
In this critical review we cover the state of the art of surface deposition of complex magnetic
molecules. Deposition methods are reviewed, as well as the most used types of surfaces …

Lanthanide SMMs based on belt macrocycles: Recent advances and general trends

Y Gil, A Castro‐Alvarez, P Fuentealba… - … A European Journal, 2022 - Wiley Online Library
Enhancement of axial magnetic anisotropy is the central objective to push forward the
performance of Single‐Molecule Magnet (SMM) complexes. In the case of mononuclear …

Effect of substituted 2, 2′-bipyridine derivatives on luminescence characteristics of green emissive terbium complexes: Spectroscopic and optical analysis

A Dalal, A Hooda, K Nehra, D Singh, S Kumar… - Journal of Molecular …, 2022 - Elsevier
Heteroleptic ternary terbium complexes with general representation as [Tb (acac) 3 L] have
been prepared through single step path with acetylacetone (acac) as chromophoric and …

Approaching the uniaxiality of magnetic anisotropy in single-molecule magnets

C Wang, YS Meng, SD Jiang, BW Wang… - Science China Chemistry, 2023 - Springer
Abstract Single-molecule magnets (SMMs), which can exhibit slow magnetization relaxation
and bulk-magnet-like hysteresis of purely molecular origin, are promising candidates for …

Theoretical Insights into the Adsorption of Rare-Earth-Containing Single-Molecule Magnets on Solid Surfaces

JC Ren, J Zhou, S Li, W Liu - The Journal of Physical Chemistry C, 2023 - ACS Publications
Single-molecule magnets (SMMs) offer stable quantum objects capable of exhibiting diverse
magnetic states on the nanoscale, making them promising candidates for storing and …

A Combined Synthetic, Magnetic, and Theoretical Study on Enhancing Ligand-Field Axiality for Dy (III) Single-Molecule Magnets Supported by Ferrocene Diamide …

K Yang, R Sun, J Zhao, C Deng, B Wang… - Inorganic …, 2023 - ACS Publications
Molecular design is crucial for improving the performance of single-molecule magnets
(SMMs). For dysprosium (III) SMMs, enhancing ligand-field axiality is a well-suited strategy …

Single-Ion Magnets with Giant Magnetic Anisotropy and Zero-Field Splitting

M Georgiev, H Chamati - ACS omega, 2022 - ACS Publications
The design of mononuclear molecular nanomagnets exhibiting a huge energy barrier to the
reversal of magnetization have seen a surge of interest during the last few decades due to …

Slow magnetic relaxation in a homoaxially phosphine oxide coordinated pentagonal bipyramidal Dy (III) complex

P Kalita, N Ahmed, S Moorthy, V Béreau, AK Bar… - Dalton …, 2023 - pubs.rsc.org
We report the synthesis of [(L) DyIII (Cy3PO) 2]·[BPh4](1-Dy)(where H2L= 2, 6-
diacetylpyridine bis-benzoylhydrazone and Cy= cyclohexyl) which crystallized in the triclinic …

Understanding electrostatics and covalency effects in highly anisotropic organometallic sandwich dysprosium complexes [Dy (C m R m) 2](where R= H, SiH 3, CH 3 …

I Tarannum, S Moorthy, SK Singh - Dalton Transactions, 2023 - pubs.rsc.org
In this article, we have thoroughly studied the electronic structure and 4f-ligand covalency of
six mononuclear dysprosium organometallic sandwich complexes [Dy (CmRm) 2] …

Boosting the mono-axial crystal field in stable high-coordinate Dy (III) single-ion magnets by substitution of the phenoxy axial ligand

B Zhang, Y Zhou, C Dong, Y Xiang, Y Shi… - Dalton …, 2023 - pubs.rsc.org
Synthesis of air-stable and high-performance single-molecule magnets (SMMs) is
challenging. Here, a heptadentate pentapyridyldiamine (BPA-TPA) ligand and fine-tuned …