Recent advances in directed C–H functionalizations using monodentate nitrogen-based directing groups

M Zhang, Y Zhang, X Jie, H Zhao, G Li… - Organic Chemistry …, 2014 - pubs.rsc.org
The use of directing groups has proven to be a successful strategy to enhance reactivity and
control selectivity in C–H functionalization reactions. In the past decade, a multitude of new …

New Approaches for Biaryl-Based Phosphine Ligand Synthesis via P O Directed C–H Functionalizations

YN Ma, SX Li, SD Yang - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus Given the important influence of phosphine ligands in transition metal-catalyzed
reactions, chemists have searched for straightforward and efficient methodologies for the …

Recent advances in palladium-catalyzed C (sp3)–H activation for the formation of carbon–carbon and carbon–heteroatom bonds

N Dastbaravardeh, M Christakakou, M Haider… - …, 2014 - thieme-connect.com
Within this review, recent developments in the field of C (sp 3)–H activation catalyzed by
palladium are discussed. Both intra-and intermolecular reactions towards carbon–carbon …

Rhodium (III)-catalyzed direct coupling of arylphosphine derivatives with heterobicyclic alkenes: a concise route to biarylphosphines and dibenzophosphole …

Y Unoh, T Satoh, K Hirano, M Miura - ACS Catalysis, 2015 - ACS Publications
The redox-neutral direct coupling of arylphosphine oxides with heterobicyclic alkenes
proceeds smoothly under rhodium (III) catalysis involving hydroarylation followed by …

Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot

T Ryu, J Min, W Choi, WH Jeon, PH Lee - Organic letters, 2014 - ACS Publications
Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through
Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot | Organic Letters ACS ACS …

Palladium-catalyzed ortho-alkoxylation of 2-aryl-1, 2, 3-triazoles

S Shi, C Kuang - The Journal of Organic Chemistry, 2014 - ACS Publications
Palladium-Catalyzed Ortho-Alkoxylation of 2-Aryl-1,2,3-triazoles | The Journal of Organic
Chemistry ACS ACS Publications C&EN CAS Find my institution Log In The Journal of Organic …

Aerobic direct C (sp2)-H hydroxylation of 2-arylpyridines by palladium catalysis induced with aldehyde auto-oxidation

P Das, D Saha, D Saha, J Guin - ACS Catalysis, 2016 - ACS Publications
Herein we present a Pd-catalyzed direct C–H hydroxylation of 2-arylpyridines using
molecular oxygen (O2) as the sole oxidant. The key aspects of the method include:(a) the …

Synthesis of Indolo‐1, 2‐Benzothiazines from Sulfoximines and 3‐Diazoindolin‐2‐imines

GH Ko, JY Son, H Kim, C Maeng, Y Baek… - Advanced Synthesis …, 2017 - Wiley Online Library
A rhodium‐catalyzed cyclization reaction of sulfoximines with 3‐diazoindolin‐2‐imines is
described. This protocol provides a wide range of indolo‐1, 2‐benzothiazines in moderate to …

Palladium-Catalyzed Aryl C(sp2)–H Bond Hydroxylation of 2-Arylpyridine Using TBHP as Oxidant

J Dong, P Liu, P Sun - The Journal of Organic Chemistry, 2015 - ACS Publications
An efficient synthesis of phenols via Pd-catalyzed, pyridyl-directed homogeneous
hydroxylation of the aryl C–H bond was developed, in which tert-butyl hydroperoxide was …

Selective Rhodium-Catalyzed C–H Amidation of Azobenzenes with Dioxazolones under Mild Conditions

B Jeon, U Yeon, JY Son, PH Lee - Organic letters, 2016 - ACS Publications
A synthetic method for a wide range of amidated azobenzenes is developed from the
selective rhodium-catalyzed C–H amidation reaction of symmetrical as well as …