Hydronium ion and water complexes vs. methanol on solid catalyst surfaces: how confinement influences stability and reactivity
Z Li, D Dittmann, C Rieg, M Benz… - Catalysis Science & …, 2022 - pubs.rsc.org
Water and alcohols like methanol are key substrates in catalysis. Thus, adsorption on
catalysts plays a key role in chemical reactions. Herein we investigate how surface sites and …
catalysts plays a key role in chemical reactions. Herein we investigate how surface sites and …
Correlating Surface Chemistry to Surface Relaxivity via TD-NMR Studies of Polymer Particle Suspensions
MT Suekuni, AM Allgeier - JACS Au, 2023 - ACS Publications
This study elucidates the impact of surface chemistry on solvent spin relaxation rates via
time-domain nuclear magnetic resonance (TD-NMR). Suspensions of polymer particles of …
time-domain nuclear magnetic resonance (TD-NMR). Suspensions of polymer particles of …
Catalytic Cracking of 1, 3, 5‐Triisopropylbenzene and Low‐Density Polyethylene over Hierarchical Y Zeolites and Al‐SBA‐15
Catalytic cracking of high molecular weight hydrocarbons underpins the production of fossil
fuels from petroleum vapour and the recycling of polyolefin waste plastic. However, thermal …
fuels from petroleum vapour and the recycling of polyolefin waste plastic. However, thermal …
NMR surface relaxivity in a time-dependent porous system
N Robinson, R Nasharuddin, EO Fridjonsson… - Physical Review Letters, 2023 - APS
We demonstrate an unexpected decay-recovery behavior in the time-dependent H 1 NMR
relaxation times of water confined within a hydrating porous material. Our observations are …
relaxation times of water confined within a hydrating porous material. Our observations are …
[HTML][HTML] Petrophysical evaluation of the Lower Permian formation as a potential reservoir for CO2-EGS–Case study from NW Poland
Petrophysical evaluation of the Lower Permian formation was performed on the basis of the
results of laboratory tests of rocks including pore space investigations using the Mercury …
results of laboratory tests of rocks including pore space investigations using the Mercury …
[HTML][HTML] Adsorbate/adsorbent interactions in microporous zeolites: Mechanistic insights from NMR relaxation and DFT calculations
Nuclear magnetic resonance (NMR) relaxation is an effective and non-invasive technique
for probing guest-host interactions in porous materials. In particular, the ratio of longitudinal …
for probing guest-host interactions in porous materials. In particular, the ratio of longitudinal …
[HTML][HTML] Heteropolyacids supported on zirconia-doped γ, θ and α alumina: A physicochemical assessment and characterisation of supported solid acids
In this paper we carry out a surface study of promising supported solid acid catalysts
commonly used for the production of high value chemicals derived from glycerol. In …
commonly used for the production of high value chemicals derived from glycerol. In …
Host-guest interactions and confinement effects in HZSM-5 and chabazite zeolites studied by low-field NMR spin relaxation
C D'Agostino, APE York, P Bräuer - Materials Today Chemistry, 2022 - Elsevier
The characterization of fluid/solid interactions in porous materials is crucial for their design
and optimization, most notably in applications such as adsorption and catalysis. Yet, probing …
and optimization, most notably in applications such as adsorption and catalysis. Yet, probing …
Generalized Cross-Validation as a Method of Hyperparameter Search for MTGV Regularization
JBB Beckmann, A Sparks, JA Ward-Williams… - arXiv preprint arXiv …, 2023 - arxiv.org
The concept of generalized cross-validation (GCV) is applied to modified total generalized
variation (MTGV) regularization. Current implementations of the MTGV regularization rely on …
variation (MTGV) regularization. Current implementations of the MTGV regularization rely on …
Characterizing solid–liquid interactions in a mesoporous catalyst support using variable-temperature fast field cycling NMR
J Ward-Williams, JP Korb, L Rozing… - The Journal of …, 2021 - ACS Publications
Variable-temperature fast field cycling NMR measurements are used to probe the surface
dynamics of different liquids imbibed within a γ-alumina catalyst support material. The …
dynamics of different liquids imbibed within a γ-alumina catalyst support material. The …