NMR investigation into the influence of surface interactions on liquid diffusion in a mesoporous catalyst support

N Robinson, C D'Agostino - Topics in Catalysis, 2020 - Springer
Pulsed field gradient NMR diffusion measurements provide a non-invasive measure of the
mass transport (self-diffusion) characteristics of liquids confined to porous catalyst materials …

Insights into Substituent Effects of Benzaldehyde Derivatives in a Heterogeneous Organocatalyzed Aldol Reaction

G Di Carmine, F Pesciaioli, S Wang, A Sinibaldi… - …, 2022 - Wiley Online Library
Organocatalyst immobilization onto solid supports represents a promising method for
enabling asymmetric organocatalysis while retaining the advantages of heterogeneous …

[HTML][HTML] Functional group resolved NMR relaxation of 3-carbon adsorbates in mesoporous alumina

N Robinson, C D'agostino, ML Johns - Magnetic Resonance Letters, 2023 - Elsevier
NMR relaxation analysis provides a unique and non-invasive probe of fluid dynamics within
porous materials, and may be applied to the interpretation of a wide variety of material and …

Characterization of Functionalized Chromatographic Nanoporous Silica Materials by Coupling Water Adsorption and Intrusion with Nuclear Magnetic Resonance …

C Schlumberger, CC Collados, J Söllner… - ACS Applied Nano …, 2024 - ACS Publications
Nanoporous silica is widely used as a support material for chemically bound stationary
phases in chromatographic separations as well as for catalytic applications. Tuning of …

Toward Quantifying the Chemical Sensitivity of Nuclear Spin Surface Relaxivity in Mesoporous Media

S Dong, L Liu, NNA Ling, EF May, ML Johns… - Langmuir, 2024 - ACS Publications
Low-field nuclear magnetic resonance (NMR) relaxation is a promising non-invasive
technique for characterizing solid–liquid interactions within functional porous materials …

Investigating the behaviour of NaCl brines and hydrocarbons in porous alumina using low-field NMR relaxation and diffusion methods

A Mavridis, M Sankey, K Chellappah… - Physical Chemistry …, 2024 - pubs.rsc.org
The behaviour of multiple fluid phases within a porous medium is hard to predict. NMR
measurements offer an excellent tool to probe such systems in a fast and non-invasive way …

Capillary Trapping of CO2 in Sandstone Using Low Field NMR Relaxometry

PRJ Connolly, SJ Vogt, M Mahmoud… - Water Resources …, 2019 - Wiley Online Library
Injecting carbon dioxide into geological formations for long‐term storage is considered
integral to reducing greenhouse gas emissions. Residual trapping of CO2 is a primary …

Coverage-dependent adsorption of n-hexane and isopropanol on silica: A density-functional study

IJ Chevallier-Boutell, RH Acosta, MB Franzoni… - Microporous and …, 2024 - Elsevier
This study delves into the adsorption behavior of both polar and non-polar molecules on
silica surfaces, spanning a range from low coverage to full adsorption scenarios. Our results …

[HTML][HTML] Insight of solvent effect on CeO2 catalyzed oxidation of styrene with tert-butyl hydroperoxide: A combined experimental and theoretical approach

J Halder, T Roy, S Satpati, S Ghosal… - Catalysis …, 2022 - Elsevier
Solvents influence the energetics of adsorbates on the solvent/catalyst interface and thus
control the catalytic activity and product distribution in heterogeneous catalysis. In the …

Identification of proton populations in cherts as natural analogues of pure silica materials by means of low field NMR

AT Krzyżak, W Mazur, J Matyszkiewicz… - The Journal of …, 2020 - ACS Publications
Recent theories about the sources of silica in bedded and nodular cherts do not fit the origin
of cherts from the Kraków–Częstochowa Upland. Since siliceous sponges as a single …