Nickel-catalyzed 1, 1-aminoborylation of unactivated terminal alkenes

L Talavera, RRA Freund, H Zhang, M Wakeling… - ACS …, 2023 - ACS Publications
Herein, we disclose a Ni-catalyzed 1, 1-difunctionalization of unactivated terminal alkenes
that enables the incorporation of two different heteroatom motifs across an olefin backbone …

Pd (0)-Catalyzed Diastereoselective and Enantioselective Intermolecular Heck–Miyaura Borylation of Internal Enamides for the β-Aminoboronate Ester Synthesis

C Wang, Y Xi, T Xia, J Qu, Y Chen - ACS Catalysis, 2023 - ACS Publications
Miyaura borylation is widely recognized as one of the most reliable methods for constructing
an organoboron compound. Reported herein is Pd (0)-catalyzed asymmetric three …

Diverse Synthesis of C-Glycosides by Stereoselective Ni-Catalyzed Carboboration of Glycals

MY Lyu, SA Jacobo, MK Brown - Journal of the American …, 2024 - ACS Publications
C-Glycosides are important structures that are common to natural products and
pharmaceutical agents. Established methods for their synthesis involve the reaction of an …

Computational and Mechanistic Studies of Pd-Catalyzed Alkene Carboacylation via Ester C–O Bond Activation

M Alkan, HK Banovetz, MS Gordon, LM Stanley - ACS Catalysis, 2023 - ACS Publications
Computational and mechanistic studies of Pd-catalyzed alkene carboacylation via ester
bond activation are investigated through a combination of density functional theory (DFT) …

Mechanism and Origins of Regio-and Stereoselective Alkylboration of Endocyclic Olefins Enabled by Nickel Catalysis

M Chen, YW Gu, W Deng, ZY Xu - The Journal of Organic …, 2023 - ACS Publications
The Ni-catalyzed alkylboration of endocyclic olefins is a stereo-and regioselective approach
for the synthesis of boron-containing compounds. We report a detailed density functional …

Photoinduced Metal-Free Arylboration of Unactivated Alkenes: Synthesis of Indoline Boronic Ester

J Lu, Y He, L Ren, D Li, X Pan, L Yang, J Wang, S Wei… - Synlett, 2023 - thieme-connect.com
The environmentally benign synthesis of indoline boronic esters, especially through a way of
arylboration to alkenes, remains a challenge due to the use of transition metals or high …

Synthesis of (±)-Phyltetralin by Cu/Pd-Catalyzed Arylboration

GL Trammel, AC Kerlin, C Zachau, MK Brown - Synlett, 2023 - thieme-connect.com
Synthesis of (±)-Phyltetralin by Cu/Pd-Catalyzed Arylboration Page 1 2197 © 2023. Thieme.
All rights reserved. Synlett 2023, 34, 2197–2199 Georg Thieme Verlag KG, Rüdigerstraße …

[引用][C] Saturated (C (sp3) B) Boronic Acid Derivatives

DJ Konowalchuk, OM Schneider, DG Hall - 2024 - Elsevier