Carbene‐Catalyzed Asymmetric Construction of Atropisomers

R Song, Y Xie, Z Jin, YR Chi - Angewandte Chemie, 2021 - Wiley Online Library
Atropisomeric molecules have found proven applications and have shown promising
potential in chemistry and medicine. The design of N‐heterocyclic carbene (NHC) catalyzed …

Metal-Catalyzed Enantioconvergent Transformations

M Yus, C Nájera, F Foubelo, JM Sansano - Chemical Reviews, 2023 - ACS Publications
Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Asymmetric catalysis mediated by synthetic peptides, version 2.0: expansion of scope and mechanisms

AJ Metrano, AJ Chinn, CR Shugrue, EA Stone… - Chemical …, 2020 - ACS Publications
Low molecular weight synthetic peptides have been demonstrated to be effective catalysts
for an increasingly wide array of asymmetric transformations. In many cases, these peptide …

Versatile synthetic platform for 1, 2, 3-triazole chemistry

DP Vala, RM Vala, HM Patel - Acs Omega, 2022 - ACS Publications
1, 2, 3-Triazole scaffolds are not obtained in nature, but they are still intensely investigated
by synthetic chemists in various fields due to their excellent properties and green synthetic …

[HTML][HTML] Immobilisation and application of lipases in organic media

P Adlercreutz - Chemical Society Reviews, 2013 - pubs.rsc.org
Different methods of preparing lipases for use in organic media are critically reviewed. Solid
lipase preparations can be made by typical immobilisation methods such as adsorption …

Peptide-based catalysts reach the outer sphere through remote desymmetrization and atroposelectivity

AJ Metrano, SJ Miller - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Nature's catalytic machinery has provided endless inspiration for chemists.
While the enzymatic ideal has yet to be fully realized, the field has made tremendous strides …

Catalytic desymmetrization reactions to synthesize all-carbon quaternary stereocentres

P Xu, F Zhou, L Zhu, J Zhou - Nature Synthesis, 2023 - nature.com
The term all-carbon quaternary stereocentre refers to a chiral carbon atom featuring four
different carbon substituents. Such structural motifs are prominent in natural products, drugs …

N-Heterocyclic carbene-catalyzed enantioselective (dynamic) kinetic resolutions and desymmetrizations

Y Zhang, H Cai, X Gan, Z Jin - Science China Chemistry, 2024 - Springer
N-heterocyclic carbene-catalyzed enantioselective kinetic resolutions, dynamic kinetic
resolutions, and desymmetrization reactions are systematically reviewed. The content is …

Recent advances in asymmetric organocatalysis mediated by bifunctional amine–thioureas bearing multiple hydrogen-bonding donors

X Fang, CJ Wang - Chemical Communications, 2015 - pubs.rsc.org
Organocatalysis has proven to be one of the most rapidly developing and competitive
research areas in asymmetric catalysis since 2000, and has become a third branch besides …

[PDF][PDF] Green Chemistry and Catalysis

RA Sheldon - 2007 - catalysis.eprints.iitm.ac.in
This first book to focus on catalytic processes from the viewpoint of green chemistry presents
every important aspect:? Numerous catalytic reductions and oxidations methods? Solid-acid …