Transition-metal-catalyzed decarbonylation via carbon–carbon bond cleavage is an
essential synthetic methodology. Given the ubiquity of carbonyl compounds, the selective …

The gem-difluoroalkenes and related compounds have gained much attention from the
organic synthetic community due to their widespread applications as versatile fluorinated …

Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of
transition metal and lanthanide systems. Although the C–H bond is weaker than the C–F …

Much progress has been made in the development of methods to both create compounds
that contain C− F bonds and to functionalize C− F bonds. As such, C− F bonds are becoming …

Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …

A highly selective and general photocatalytic C–F borylation protocol that employs a
rhodium biphenyl complex as a triplet sensitizer and the nickel catalyst [Ni (IMes) 2](IMes= 1 …

A Ni-catalyzed borylation via C–F activation is described. This protocol is distinguished by a
wide scope, including unactivated fluoroarenes, without compromising its efficiency and …

The [Ni (IMes) 2]-catalyzed transformation of fluoroarenes into arylboronic acid pinacol
esters via C–F bond activation and transmetalation with bis (pinacolato) diboron (B2pin2) is …