Synthesis and Deconstruction of Polyethylene-type Materials

ST Schwab, M Baur, TF Nelson, S Mecking - Chemical Reviews, 2024 - ACS Publications
Polyethylene deconstruction to reusable smaller molecules is hindered by the chemical
inertness of its hydrocarbon chains. Pyrolysis and related approaches commonly require …

Recent Advances in Environmentally Friendly Dual‐crosslinking Polymer Networks

M Zhang, W Choi, M Kim, J Choi, X Zang… - Angewandte Chemie …, 2024 - Wiley Online Library
Environmentally friendly crosslinked polymer networks feature degradable covalent or non‐
covalent bonds, with many of them manifesting dynamic characteristics. These attributes …

Accurate Determination of Reactivity Ratios for Copolymerization Reactions with Reversible Propagation Mechanisms

DJ Lundberg, LJ Kilgallon, JC Cooper… - …, 2024 - ACS Publications
An understanding of monomer sequence is required to predict and engineer the properties
of copolymers. In stochastic polymerizations involving more than one monomer, monomer …

Main-Chain Carborane-Embedded Polyethylene

J Zhang, Z Meng, Y He, Z Luo, X Li, Y Sha - Macromolecules, 2024 - ACS Publications
Functionalization of polyethylene toward high-performance polymers with good thermal and
mechanical properties is a persistent challenge. Closo-carboranes, with a polyhedral …

Polymers from Plant Oils Linked by Siloxane Bonds for Programmed Depolymerization

C Cheng, JX Shi, EH Kang, TF Nelson… - Journal of the …, 2024 - ACS Publications
The increased production of plastics is leading to the accumulation of plastic waste and
depletion of limited fossil fuel resources. In this context, we report a strategy to create …

Towards sustainability and a circular Economy: ROMP for the goal of fully degradable and chemically recyclable polymers

VB Purohit, M Pięta, J Pietrasik, CM Plummer - European Polymer Journal, 2024 - Elsevier
Over the past century the advancement of polymer chemistry has provided civilization with a
plethora of plastic products that have significantly contributed to day-to-day life and the …

Tandem Olefin Metathesis Polymerization to Access Degradable and Recyclable Thermosets, Thermoplastics, and Elastomers

G Si, Z Wang, C Zou, C Chen - CCS Chemistry, 2024 - chinesechemsoc.org
The development of degradable polymers represents an appealing strategy to address ever-
growing concerns for treating waste plastics. Olefin metathesis polymerization has been …

Chemically recyclable rosin-based polymers

Y Sha, X Chen, W Sun, Y Hu, C Wang, E Xu… - European Polymer …, 2024 - Elsevier
The pursuit of next-generation sustainable polymers with chemical recyclability and
resource renewability has become a priority in materials science. Rosin, a widely available …

Synthesis of Degradable Polyethylene and Poly(ethylene-co-vinyl acetate) by Radical Co- and Terpolymerization of Ethylene, ε-Thionocaprolactone, and Vinyl …

ND Vu, O Ivanchenko, F Baffie, Y Guillaneuf… - …, 2024 - ACS Publications
We report the synthesis of PE and poly (ethylene-co-vinyl acetate)(EVA) bearing a low
content of in-chain thioester functions introduced via a co-or terpolymerization approach …

Degradable Melamine-Based Adhesives Using Dynamic Silyl Ether Bonds

IC Pierce, J Barroso, JB Ko… - ACS Applied Polymer …, 2024 - ACS Publications
Materials made from covalently cross-linked polymer networks are ubiquitous in everyday
life but are difficult to process at the end of their life cycle. Therefore, it is essential to design …