Computational discovery of transition-metal complexes: from high-throughput screening to machine learning

A Nandy, C Duan, MG Taylor, F Liu, AH Steeves… - Chemical …, 2021 - ACS Publications
Transition-metal complexes are attractive targets for the design of catalysts and functional
materials. The behavior of the metal–organic bond, while very tunable for achieving target …

Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Symmetry-supported magnetic blocking at 20 K in pentagonal bipyramidal Dy (III) single-ion magnets

YC Chen, JL Liu, L Ungur, J Liu, QW Li… - Journal of the …, 2016 - ACS Publications
Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states
separated by an energy barrier are among the most promising candidates for high-density …

Reading and writing single-atom magnets

FD Natterer, K Yang, W Paul, P Willke, T Choi, T Greber… - Nature, 2017 - nature.com
The single-atom bit represents the ultimate limit of the classical approach to high-density
magnetic storage media. So far, the smallest individually addressable bistable magnetic bits …

Two-coordinate Co (II) imido complexes as outstanding single-molecule magnets

XN Yao, JZ Du, YQ Zhang, XB Leng… - Journal of the …, 2017 - ACS Publications
The pursuit of single-molecule magnets (SMMs) with better performance urges new
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …

Understanding the magnetic anisotropy toward single-ion magnets

YS Meng, SD Jiang, BW Wang… - Accounts of chemical …, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Recent advances in luminescent lanthanide based Single-Molecule Magnets

J Long, Y Guari, RAS Ferreira, LD Carlos… - Coordination Chemistry …, 2018 - Elsevier
Abstract Luminescent lanthanide-based Single-Molecule Magnets (SMM) are multifunctional
molecule-based materials that combine luminescence and magnetic properties in the same …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …