Molecular catalysts with diphosphine ligands containing pendant amines
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
[HTML][HTML] Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
Electro-and solar-driven fuel synthesis with first row transition metal complexes
KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …
major step toward creating sustainable and scalable energy storage technologies. In the last …
Tackling the challenges of enzymatic (bio) fuel cells
The ever-increasing demands for clean and sustainable energy sources combined with
rapid advances in biointegrated portable or implantable electronic devices have stimulated …
rapid advances in biointegrated portable or implantable electronic devices have stimulated …
[HTML][HTML] Semi-biological approaches to solar-to-chemical conversion
This review presents a comprehensive summary of the recent development in semi-artificial
photosynthesis, a biological-material hybrid approach to solar-to-chemical conversion that …
photosynthesis, a biological-material hybrid approach to solar-to-chemical conversion that …
Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …
W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …
fuels have stimulated extensive research to identify new energy systems and economies that …
[HTML][HTML] Structural basis for bacterial energy extraction from atmospheric hydrogen
Diverse aerobic bacteria use atmospheric H2 as an energy source for growth and survival.
This globally significant process regulates the composition of the atmosphere, enhances soil …
This globally significant process regulates the composition of the atmosphere, enhances soil …
Hydrogenases
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
Scope and prospect of transition metal-based cocatalysts for visible light-driven photocatalytic hydrogen evolution with graphitic carbon nitride
The photocatalytic production of H 2 using sunlight is considered a sustainable solution to
fulfill the global energy demand and reduce the emission of greenhouse gases generated …
fulfill the global energy demand and reduce the emission of greenhouse gases generated …
Enzymatic biofuel cells: 30 years of critical advancements
M Rasmussen, S Abdellaoui, SD Minteer - Biosensors and Bioelectronics, 2016 - Elsevier
Enzymatic biofuel cells are bioelectronic devices that utilize oxidoreductase enzymes to
catalyze the conversion of chemical energy into electrical energy. This review details the …
catalyze the conversion of chemical energy into electrical energy. This review details the …