[HTML][HTML] Double boron-embedded multiresonant thermally activated delayed fluorescent materials for organic light-emitting diodes

KR Naveen, HI Yang, JH Kwon - Communications Chemistry, 2022 - nature.com
The subclass of multi resonant thermally activated delayed fluorescent emitters (MR-TADF)
containing boron atoms has garnered significant attention in the field of organic light emitting …

Polycyclic Aromatic Hydrocarbon‐based Soft Materials: Applications in Fluorescent Detection, Gelation, AIEE and Mechanochromism

H Goyal, P Kumar, R Gupta - Chemistry–An Asian Journal, 2023 - Wiley Online Library
The present review discusses selected compounds based on polycyclic aromatic
hydrocarbons (PAHs); mainly those containing naphthalene, anthracene, fluorene, pyrene …

Ribbon‐Type Boron‐Doped Polycyclic Aromatic Hydrocarbons: Conformations, Dynamic Complexation and Electronic Properties

W Sun, J Guo, Z Fan, L Yuan, K Ye… - Angewandte Chemie …, 2022 - Wiley Online Library
Abstract Molecular ribbons (MRs), one‐dimentional topological polycyclic aromatic
hydrocarbons (PAHs), are of importance for synthetic chemistry and material sciences …

Photonic Modulation Enabled by Controlling the Edge Structures of Boron‐Doped Molecular Carbons

Y Liu, L Yuan, J Guo, W Sun, Y Wang… - Angewandte …, 2023 - Wiley Online Library
Control over topological edges of molecular carbons (MCs) is of importance for achieving
diverse molecular topologies and desirable physical properties. However, it remains very …

[HTML][HTML] Fully-fused boron-doped olympicenes: modular synthesis, tunable optoelectronic properties, and one-electron reduction

J Guo, K Zhang, Y Wang, H Wei, W Xiao, K Yang… - Chemical …, 2023 - pubs.rsc.org
We report here a novel family of boraolympicenes, structurally featuring boron-doping at the
concave 11a-position of their π-skeletons and synthetically prepared via a facile one-pot …

Photodissociative Modules that Control Dual‐Emission Properties in Donor–π–Acceptor Organoborane Fluorophores

M Kawashiro, T Mori, M Ito, N Ando… - Angewandte …, 2023 - Wiley Online Library
Donor–π–acceptor fluorophores that consist of an electron‐donating amino group and an
electron‐accepting triarylborane moiety generally exhibit substantial solvatochromism in …

B2,N4-Doped Heptacenes: Ambipolar Charge-Transfer Compounds with Deep LUMO Levels

M Metzler, A Virovets, HW Lerner… - Journal of the American …, 2023 - ACS Publications
The B2, N4-doped heptacene H4 in which two N, N′-dihydrophenazine units are linked by
two BMes bridges (Mes= mesityl) was synthesized via fourfold Buchwald− Hartwig coupling …

Fusion of Aza‐and Oxadiborepins with Furans in a Reversible Ring‐Opening Process Furnishes Versatile Building Blocks for Extended π‐Conjugated Materials

J Bachmann, A Helbig, M Crumbach… - … A European Journal, 2022 - Wiley Online Library
A modular synthesis of both difurooxa‐and difuroazadiborepins from a common precursor is
demonstrated. Starting from 2, 2′‐bifuran, after protection of the positions 5 and 5'with …

Diradicaloid Boron‐Doped Molecular Carbons Achieved by Pentagon‐Fusion

L Yuan, J Yang, S Qi, Y Liu, X Tian, T Jia… - Angewandte …, 2023 - Wiley Online Library
Molecular carbons (MCs) are molecular cutouts of carbon materials. Doping with
heteroatoms and constructing open‐shell structures are two powerful approaches to achieve …

Flow‐Chemistry‐Enabled Synthesis of 5‐Diethylboryl‐2, 3′‐bipyridine and Its Self‐Assembly Dynamics

S Wakabayashi, M Takumi, S Kamio… - … A European Journal, 2023 - Wiley Online Library
Diethylboryl‐2, 3′‐bipyridine (1), which is inaccessible by conventional batch methods,
was synthesized by using a flow microreactor. Compound 1 was obtained as an equilibrium …