Small-ring chemistry is a fascinating field in organic chemistry. gem-Difluorinated
cyclopropanes, a unique class of cyclopropanes, have garnered significant interest due to …

A novel enantioselective Tsuji–Trost‐type cross coupling reaction between gem‐
difluorinated cyclopropanes and N‐unprotected amino acid esters enabled by synergistic …

A switchable synthesis of alcohols and ketones bearing a CF2–OR scaffold using visible-
light promotion is described. The method of PDI catalysis is characterized by its ease of …

The (3+ 2) cycloaddition/sulfur rearrangement reaction of donor–acceptor cyclopropanes
bearing a single keto acceptor with indoline-2-thiones has been realized. Under the …

An electrochemical methodology for the construction of α‐CF3‐substituted carbonyl
compounds in moderate to good yields under exogenous metal and oxidant‐free conditions …

Metathesis reactions have been established as a powerful tool in organic synthesis. While
great advances were achieved in double-bond metathesis, like olefin metathesis and …

Visible light-induced reactions are a rapidly developing and powerful technique to promote
organic transformations. They provide green and sustainable chemistry and have recently …

Transition‐metal (TM) catalyzed reaction of gem‐difluorinated cyclopropanes (gem‐DFCPs)
has drawn much attention recently. The reaction generally occurs via the activation of the …

In this study, concise, efficient, and modular hydrophosphinylation and hydroamidation of
gem-difluorocyclopropenes were disclosed in a mild and transition-metal-free pattern …

Aromaticity is a fundamental concept in organic chemistry. Hyperconjugative aromaticity,
also known as hyperconjugation-induced aromaticity, has evolved from its origin from main …