The electrodeposition of Au on Pt (111) from electrolytes containing μM concentrations of
AuCl4-was studied by in situ scanning tunneling microscopy. Under these conditions the Au …

The assumption that “OHads” or other oxygen containing species is formed on
polycrystalline or nanoparticulate platinum through a fast and reversible process at relatively …

Much work over the past several decades has demonstrated that the vibrational frequencies
of adsorbates on metal surfaces in ultra-high vacuum (UHV) shift with changing surface …

Attenuated total reflection infrared (ATR-IR) spectroscopy has been combined with
electrochemical methods to investigate molecular decomposition and self-poisoning …

The role of alkali cations potassium and caesium on the structure of the interfacial region
between a Pt (111) electrode and a sulphuric acid solution is investigated by cyclic …

Stepped Pt surfaces having different width (1 1 1) terraces interrupted by (1 1 0) or (1 0 0)
monoatomic steps were employed to evaluate the catalytic activity toward CO oxidation at Pt …

The mechanism of the electrochemical adsorption of bisulfate, sulfate, and oxygen on
polycrystalline gold in H 2 SO 4 (0.5 M) was modeled using a mechanistic analysis of …

The electrochemical quartz-crystal nanobalance (EQCN) measures in situ mass changes
associated with interfacial electrode processes. Real electrodes are not atomically flat, thus …

The adsorption of citrate anions on Pt {hkl} single crystal electrodes and Pt nanoparticles
was investigated using cyclic voltammetry (CV). Citrate is found to behave as a simple …

The key to understand metal/electrolyte interfaces is the “electrochemical double layer,”
which consists of a charged metal surface and a near‐surface regime enriched with ions of …