Recent advances in the applications of porous organic cages

D Hu, J Zhang, M Liu - Chemical Communications, 2022 - pubs.rsc.org
Porous organic cages (POCs) have emerged as a new sub-class of porous materials that
stand out by virtue of their tunability, modularity, and processability. Similar to other porous …

Metal–organic cages against toxic chemicals and pollutants

EG Percástegui - Chemical Communications, 2022 - pubs.rsc.org
The continuous release of toxic chemicals and pollutants into the atmosphere and natural
waters threatens, directly and indirectly, human health, the sustainability of the planet, and …

Post‐Assembly Modification of Homochiral Titanium–Organic Cages for Recognition and Separation of Molecular Isomers

GH Chen, YP He, Y Yu, H Lv, S Li… - Angewandte Chemie …, 2023 - Wiley Online Library
A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a
post‐assembly modification strategy, which made it easier to study the host–guest chemistry …

[HTML][HTML] Improving the gas sorption capacity in lantern-type metal–organic polyhedra by a scrambled cage method

BD Suso, Z Wang, AR Kennedy, AJ Fletcher… - Chemical …, 2024 - pubs.rsc.org
The synthesis of multivariate metal–organic frameworks (MOFs) is a well-known method for
increasing the complexity of porous frameworks. In these materials, the structural differences …

Ce-hydroxamate metal–organic frameworks for photocatalytic H 2 generation

X Feng, W Li, L Yang, T Song, Z Xia, Q Lai… - Chemical …, 2022 - pubs.rsc.org
Exploring the rich coordination chemistry of Ce, here we report two new entries in the
emerging category of hydroxamate-based metal–organic frameworks (MOFs). The two Ce …

Structural Diversity in Ga/In-Hydroxamate Metal–Organic Materials

W Wu, Z Qin, X Duan, Y Qiu, W Tang, C Xiong… - Inorganic …, 2024 - ACS Publications
Developing metal–organic materials (MOMs) with chemical robustness is a prerequisite to
exploring their intriguing properties and applications. As part of a continuing effort to …

Synthesis, structure and functions of discrete titanium-based multinuclear architectures

M Scarpi-Luttenauer, P Mobian, L Barloy - Coordination Chemistry Reviews, 2022 - Elsevier
An overview of organometallic or coordination multinuclear titanium complexes published so
far is given herein. The majority of these compounds are supramolecular homonuclear …

Statistical distribution of binary ligands within rhodium–organic octahedra tunes microporosity in their assemblies

T Tateishi, J Troyano, S Tokuda, GA Craig… - Inorganic …, 2024 - ACS Publications
Structure–porosity relationships for metal–organic polyhedra (MOPs) are hardly investigated
because they tend to be amorphized after activation, which inhibits crystallographic …

[HTML][HTML] Imparting structural robustness of metal–organic cages based on oxo-dimolybdenum clusters

S Delaporte, IA Lázaro, J López-Cabrelles… - Dalton …, 2023 - pubs.rsc.org
A family of robust and stable molybdenum-based metal–organic cages have been obtained
based on the [Mo2O2 (μ2-O) 2] 2+ secondary building unit. The resulting cages are …

[HTML][HTML] Solid-catalyzed synthesis of isomers–free terpinen–4–ol

F Garnes–Portolés, C López–Cruz… - Molecular …, 2022 - Elsevier
Terpinen–4–ol is a natural product with wide application in the fragrance and agrochemical
industry, currently extracted from tea tree oil or synthesized from either base–promoted …