Molecular electronics: creating and bridging molecular junctions and promoting its commercialization

T Li, VK Bandari, OG Schmidt - Advanced Materials, 2023 - Wiley Online Library
Molecular electronics is driven by the dream of expanding Moore's law to the molecular level
for next‐generation electronics through incorporating individual or ensemble molecules into …

Scalable fabrication of metallic nanogaps at the sub‐10 nm level

S Luo, BH Hoff, SA Maier, JC de Mello - Advanced Science, 2021 - Wiley Online Library
Metallic nanogaps with metal–metal separations of less than 10 nm have many applications
in nanoscale photonics and electronics. However, their fabrication remains a considerable …

[HTML][HTML] The influence of the substrate on the functionality of spin crossover molecular materials

S Yazdani, J Phillips, TK Ekanayaka, R Cheng… - Molecules, 2023 - mdpi.com
Spin crossover complexes are a route toward designing molecular devices with a facile
readout due to the change in conductance that accompanies the change in spin state …

Top-down nanofabrication approaches toward single-digit-nanometer scale structures

DK Oh, H Jeong, J Kim, Y Kim, I Kim, JG Ok… - Journal of Mechanical …, 2021 - Springer
Sub-10 nm nanostructures have received broad interest for their intriguing nano-optical
phenomena, such as extreme field localization and enhancement, quantum tunneling effect …

[HTML][HTML] Spin-crossover complexes in direct contact with surfaces

M Gruber, R Berndt - Magnetochemistry, 2020 - mdpi.com
The transfer of the inherent bistability of spin crossover compounds to surfaces has attracted
considerable interest in recent years. The deposition of the complexes on surfaces allows …

Review of Fe-based spin crossover metal complexes in multiscale device architectures

N Amin, SM Said, MFM Salleh, AM Afifi, N Ibrahim… - Inorganica Chimica …, 2023 - Elsevier
Metal complexes involving d 4-d 7 first-row transition metals exhibit spin-crossover (SCO)
behaviour between low-spin and high-spin states in response to external stimuli such as …

[HTML][HTML] Room temperature conductance switching in a molecular iron (iii) spin crossover junction

SK Karuppannan, A Martín-Rodríguez, E Ruiz… - Chemical …, 2021 - pubs.rsc.org
Herein, we report the first room temperature switchable Fe (III) molecular spin crossover
(SCO) tunnel junction. The junction is constructed from [FeIII (qsal-I) 2] NTf2 (qsal-I= 4-iodo-2 …

[HTML][HTML] Defying the inverse energy gap law: a vacuum-evaporable Fe (ii) low-spin complex with a long-lived LIESST state

J Grunwald, J Torres, A Buchholz, C Näther… - Chemical …, 2023 - pubs.rsc.org
The novel vacuum-evaporable complex [Fe (pypypyr) 2](pypypyr= bipyridyl pyrrolide) was
synthesised and analysed as bulk material and as a thin film. In both cases, the compound is …

A tutorial on electrochemical impedance spectroscopy and nanogap electrodes for biosensing applications

NT Kemp - IEEE Sensors Journal, 2021 - ieeexplore.ieee.org
Electrochemical Impedance Spectroscopy (EIS) is a powerful measurement technique used
by scientists and engineers to characterize and understand the interfacial behavior of liquid …

Electron-induced spin-crossover in self-assembled tetramers

S Johannsen, S Ossinger, T Markussen, F Tuczek… - ACS …, 2021 - ACS Publications
The spin crossover compound Fe (H2B (pyrazole)(pyridylpyrazole)) 2 was investigated in
detail on Ag (111) with scanning tunneling microscopy (STM). A large fraction of the …