The cytochromes P450 comprise a large superfamily of heme monooxygenases with a
conserved fold and a cysteine-ligated heme that catalyze oxygen insertion into a large …

Atomically precise pieces of metal matter–with nanometre dimensions–are new categories
of materials with many unusual properties. Giant advances in science and technology have …

Metal–organic frameworks (MOFs) represent one of the most topical fields in modern
chemistry with novel directions emerging on a regular basis. Since the inception of the field …

C–H bonds are the most ubiquitous functional groups found in nature. While C–H bonds are
abundant, they are oxidatively robust due to the lack of polarity about the C–H bond and …

Iron is the second most abundant metal on earth and its compounds are used in various
fields. For instance, Fe3O4 particles are used as MRI contrast agents, 1) catalysts, 2) and …

Natural metalloenzymes stabilize reactive intermediates through specific metal-substrate
interactions in protein confinement. Using the structural blueprint of enzyme pockets it is …

The study of porous materials dates back centuries to the discovery of activated charcoal
used in holistic remedies across the globe. The recent advances in these materials have …

Abstract Metal-Organic Frameworks (MOFs) are a class of porous materials that are
applicable in many energy and environmentally relevant areas, due to their unique features …

The selective functionalization of simple hydrocarbons would provide opportunities to utilize
currently wasted hydrocarbon fractions as chemical fuels and chemical feedstocks. We are …

Ordered crystalline microporous materials including metal organic frameworks (MOFs),
zeolite imidazolate frameworks (ZIFs), and covalent organic frameworks (COFs) have …