Spontaneous deracemizations

T Buhse, JM Cruz, ME Noble-Teran… - Chemical …, 2021 - ACS Publications
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …

Vibrational optical activity for structural characterization of natural products

PL Polavarapu, E Santoro - Natural Product Reports, 2020 - pubs.rsc.org
Covering: 2015 to up to 2019 This review presents the recent progress towards elucidating
the structures of chiral natural products and applications using vibrational optical activity …

Lanthanides complexes–Chiral sensing of biomolecules

K Staszak, K Wieszczycka, V Marturano… - Coordination Chemistry …, 2019 - Elsevier
Thanks to their dimensional versatility and ability to form complexes, lanthanides are
increasingly employed for the chiral sensing of biomolecules. In this work two sensing …

Structure of condensed phase peptides: Insights from vibrational circular dichroism and Raman optical activity techniques

TA Keiderling - Chemical reviews, 2020 - ACS Publications
Peptides and proteins are naturally chiral molecular systems so that sensing their structure
and conformation with chirality-based spectral methods is an obvious and long-used …

Terahertz circular dichroism spectroscopy of molecular assemblies and nanostructures

WJ Choi, SH Lee, BC Park… - Journal of the American …, 2022 - ACS Publications
Chemical, physical, biological and materials engineering disciplines use a variety of
chiroptical spectroscopies to probe geometrical and optical asymmetry in molecules and …

Optically probing the chirality of single plasmonic nanostructures and of single molecules: potential and obstacles

S Adhikari, M Orrit - ACS photonics, 2022 - ACS Publications
Circular dichroism (CD) is a standard method for the analysis of biomolecular conformation.
It is very reliable when applied to molecules, but requires relatively large amounts of …

Theory and algorithms for chiroptical properties and spectroscopies of aqueous systems

T Giovannini, F Egidi, C Cappelli - Physical Chemistry Chemical …, 2020 - pubs.rsc.org
Chiroptical properties and spectroscopies are valuable tools to study chiral molecules and
assign absolute configurations. The spectra that result from chiroptical measurements may …

Concurrent vibrational circular dichroism measurements with infrared spectroscopic imaging

Y Phal, K Yeh, R Bhargava - Analytical chemistry, 2020 - ACS Publications
Vibrational circular dichroism (VCD) spectroscopy has emerged as a powerful platform to
quantify chirality, a vital biological property that performs a pivotal role in the metabolism of …

Unveiling chiral optical constants of α-pinene and propylene oxide through ATR and VCD spectroscopy in the mid-infrared range

TG Mayerhöfer, AK Singh, JS Huang, C Krafft… - Spectrochimica Acta Part …, 2023 - Elsevier
Optical constants functions of analytes are indispensable for the effective design of
plasmonic sensors. Such sensors are potentially able to enhance the sensitivity by several …

A new horizon for vibrational circular dichroism spectroscopy: a challenge for supramolecular chirality

H Sato - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
Vibrational circular dichroism (VCD) spectroscopy is an extension of circular dichroism
spectroscopy into the infrared and near-infrared regions where vibrational transitions occur …