Carriers, quasi-particles, and collective excitations in halide perovskites

J Fu, S Ramesh, JW Melvin Lim, TC Sum - Chemical Reviews, 2023 - ACS Publications
Halide perovskites (HPs) are potential game-changing materials for a broad spectrum of
optoelectronic applications ranging from photovoltaics, light-emitting devices, lasers to …

Equation-of-Motion Methods for the Calculation of Femtosecond Time-Resolved 4-Wave-Mixing and N-Wave-Mixing Signals

MF Gelin, L Chen, W Domcke - Chemical Reviews, 2022 - ACS Publications
Femtosecond nonlinear spectroscopy is the main tool for the time-resolved detection of
photophysical and photochemical processes. Since most systems of chemical interest are …

From a one-mode to a multi-mode understanding of conical intersection mediated ultrafast organic photochemical reactions

Y Boeije, M Olivucci - Chemical Society Reviews, 2023 - pubs.rsc.org
Over the last few decades, conical intersections (CoIns) have grown from theoretical
curiosities into common mechanistic features of photochemical reactions, whose function is …

Plasmon mediated coherent population oscillations in molecular aggregates

D Timmer, M Gittinger, T Quenzel, S Stephan… - Nature …, 2023 - nature.com
The strong coherent coupling of quantum emitters to vacuum fluctuations of the light field
offers opportunities for manipulating the optical and transport properties of nanomaterials …

Higher-order multidimensional and pump–probe spectroscopies

J Lüttig, S Mueller, P Malý, JJ Krich… - The journal of physical …, 2023 - ACS Publications
Transient absorption and coherent two-dimensional spectroscopy are widely established
methods for the investigation of ultrafast dynamics in quantum systems. Conventionally, they …

π-Stacking-dependent vibronic couplings drive excited-state dynamics in perylenediimide assemblies

T Kim, C Lin, JD Schultz, RM Young… - Journal of the …, 2022 - ACS Publications
Vibronic coupling, the interplay of electronic and nuclear vibrational motion, is considered a
critical mechanism in photoinduced reactions such as energy transfer, charge transfer, and …

Quantum dynamics simulations of the 2D spectroscopy for exciton polaritons

ME Mondal, ER Koessler, J Provazza… - The Journal of …, 2023 - pubs.aip.org
We develop an accurate and numerically efficient non-adiabatic path-integral approach to
simulate the non-linear spectroscopy of exciton–polariton systems. This approach is based …

Unifying nonlinear response and incoherent mixing in action-2D electronic spectroscopy

M Bruschi, L Bolzonello, F Gallina… - The Journal of Physical …, 2023 - ACS Publications
Action-detection has expanded the scope and applicability of 2D electronic spectroscopy,
while posing new challenges for the unambiguous interpretation of spectral features. In this …

Nonlinear Optical Spectroscopy of Molecular Assemblies: What Is Gained and Lost in Action Detection?

L Bolzonello, M Bruschi, B Fresch… - The Journal of Physical …, 2023 - ACS Publications
This study elucidates the information content that is extracted from action-2D electronic
spectroscopy (A-2DES) when the output intensity is not proportional to the number of …

Mapping electronic decoherence pathways in molecules

I Gustin, CW Kim, DW McCamant… - Proceedings of the …, 2023 - National Acad Sciences
Establishing the fundamental chemical principles that govern molecular electronic quantum
decoherence has remained an outstanding challenge. Fundamental questions such as how …