[HTML][HTML] Engineering mass transport properties in oxide ionic and mixed ionic-electronic thin film ceramic conductors for energy applications

I Garbayo, F Baiutti, A Morata, A Tarancon - Journal of the European …, 2019 - Elsevier
New emerging disciplines such as Nanoionics and Iontronics are dealing with the
exploitation of mesoscopic size effects in materials, which become visible (if not …

Dislocations Accelerate Oxygen Ion Diffusion in La0.8Sr0.2MnO3 Epitaxial Thin Films

E Navickas, Y Chen, Q Lu, W Wallisch, TM Huber… - ACS …, 2017 - ACS Publications
Revealing whether dislocations accelerate oxygen ion transport is important for providing
abilities in tuning the ionic conductivity of ceramic materials. In this study, we report how …

Diffusion in energy materials: Governing dynamics from atomistic modelling

D Parfitt, A Kordatos, PP Filippatos… - Applied Physics …, 2017 - pubs.aip.org
Understanding diffusion in energy materials is critical to optimising the performance of solid
oxide fuel cells (SOFCs) and batteries both of which are of great technological interest as …

Faster Diffusion of Oxygen Along Dislocations in (La,Sr)MnO3+δ Is a Space‐Charge Phenomenon

JM Börgers, J Kler, K Ran, E Larenz… - Advanced Functional …, 2021 - Wiley Online Library
In displaying accelerated oxygen diffusion along extended defects,(La, Sr) MnO3+ δ is an
atypical acceptor‐doped perovskite‐type oxide. In this study, 18O/16O diffusion experiments …

Engineering transport in manganites by tuning local nonstoichiometry in grain boundaries

F Chiabrera, I Garbayo, L López‐Conesa… - Advanced …, 2019 - Wiley Online Library
Interface‐dominated materials such as nanocrystalline thin films have emerged as an
enthralling class of materials able to engineer functional properties of transition metal oxides …

Unveiling the Outstanding Oxygen Mass Transport Properties of Mn-Rich Perovskites in Grain Boundary-Dominated La0.8Sr0.2(Mn1–xCox)0.85O3±δ …

AM Saranya, A Morata, D Pla, M Burriel… - Chemistry of …, 2018 - ACS Publications
Ion transport in solid-state devices is of great interest for current and future energy and
information technologies. A superior enhancement of several orders of magnitude of the …

The surprisingly high activation barrier for oxygen-vacancy migration in oxygen-excess manganite perovskites

JM Börgers, RA De Souza - Physical Chemistry Chemical Physics, 2020 - pubs.rsc.org
The current description of oxygen-vacancy behaviour in (La, Sr) MnO3 perovskite-type
oxides, though widely accepted, ignores a pronounced discrepancy. Values of the activation …

[HTML][HTML] Unraveling bulk and grain boundary electrical properties in La0. 8Sr0. 2Mn1− yO3±δ thin films

F Chiabrera, I Garbayo, D Pla, M Burriel, F Wilhelm… - APL Materials, 2019 - pubs.aip.org
Grain boundaries in Sr-doped LaMnO 3±δ thin films have been shown to strongly influence
the electronic and oxygen mass transport properties, being able to profoundly modify the …

Advances in nanoengineered air electrodes: towards high-performance solid oxide cells

JD Sirvent, F Buzi, F Baiutti… - … Materials for Solid Oxide …, 2023 - iopscience.iop.org
In this chapter, we present an overview of the different approaches currently followed to
fabricate nanostructured electrodes (at the volume and surface level) as well as the reported …

Electrocatalytic surface nanoionics with strained interfaced and colossal conductivity for enhancing durability and performance of solid oxide fuel cell

Y Chen, CO Romo-De-La-Cruz… - Journal of Power …, 2022 - Elsevier
For an oxygen electrode in solid oxide fuel cells (SOFCs) consisting of mixed electrical and
ionic conducting lanthanum strontium cobalt ferrite (LSCF), it degrades due to its low …