A Palladium(0)‐Catalyzed C4 Site‐Selective C−H Difluoroalkylation of Isoquinolin‐1(2H)‐Ones

YQ Zhu, LW Hui, SB Zhang - Advanced Synthesis & Catalysis, 2021 - Wiley Online Library
Herein, we report a Palladium (0)‐catalyzed C4 site‐selective C− H difluoroalkylation of
isoquinolin‐1 (2H)‐ones through a radical pathway. The present reaction enables the …

Copper-promoted difunctionalization of unactivated alkenes with silanes

Y Xue, Z Guo, X Chen, J Li, D Zou, Y Wu… - Organic & Biomolecular …, 2022 - pubs.rsc.org
An efficient copper-catalyzed cascade difunctionalization of N-allyl anilines toward the
synthesis of silylated indolines using commercially available silanes has been reported. This …

Palladium-catalyzed carbomonofluoromethylation of unactivated alkenes: rapid access to γ-monofluoromethyl carboxylic acid derivatives

XL Liu, SJ Ji, ZJ Cai - Chemical Communications, 2024 - pubs.rsc.org
Herein, we report a palladium-catalyzed regioselective carbomonofluoromethylation of
unactivated alkenes. The reaction uses easily available fluorobis (phenylsulfonyl) methane …

[HTML][HTML] Copper-catalyzed selective C5-H bromination and difluoromethylation of 8-aminoquinoline amides using ethyl bromodifluoroacetate as the bifunctional …

C Shao, T Xu, C Chen, Q Yang, C Tang, P Chen… - RSC …, 2023 - pubs.rsc.org
A simple and effective method for the copper-catalyzed selective C5-H bromination and
difluoromethylation of 8-aminoquinoline amides with ethyl bromodifluoroacetate as the …

Metal-free regioselective C5-cyanoalkylation of the 8-aminoquinolineamides/sulfonamides via oxidative cross-dehydrogenative coupling with alkylnitriles

F Doraghi, E Kianmehr, A Foroumadi - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
A direct metal-free oxidative cross-dehydrogenative coupling of 8-aminoquinolineamides/
sulfonamides and acetonitrile is described. This protocol exhibits good tolerance toward …

Copper/silver cocatalyzed regioselective C5–H functionalization of 8-aminoquinoline amides with 1, 3-dicarbonyl compounds

F Zhan, W Zhang, H Zhao - Synthesis, 2020 - thieme-connect.com
A copper/silver co-catalyzed cross-dehydrogenative coupling reaction is developed to
achieve exclusively remote C5–H coupling of 8-aminoquinoline amides with the methylenic …

An efficient protocol for the synthesis of monofluoroalkylated (hetero) arenes via Pd-catalyzed α-(hetero) arylation of α-fluoroketones with (hetero) aryl bromides

L Ding, S Han, X Chen, L Li, J Li, D Zou, Y Wu, Y Wu - Tetrahedron Letters, 2020 - Elsevier
An efficient synthesis of monofluoroalkylated N-heteroarenes using α-fluoroketones as
monofluoroalkyl reagents was developed. A variety of novel α-(hetero) aryl-α-fluoroketones …

Six-membered ring systems: pyridines and benzo derivatives

JC Badenock - Progress in Heterocyclic Chemistry, 2021 - Elsevier
Pyridines and their benzo derivatives are versatile organic scaffolds celebrated for their
presence in a variety of agrochemicals, polymers, and pharmaceuticals. Accordingly, the …

Quinquevalent phosphorus acids

P Bałczewski, K Owsianik - 2024 - books.rsc.org
This chapter covers scientific contributions in quinquevalent organo-phosphorus chemistry
published in the literature in 2021. The review is not comprehensive but shows the most …

Tertiary phosphines: preparation and reactivity

EI Musina, AS Balueva, AA Karasik - 2021 - books.rsc.org
This chapter covers the literature published during 2019 relating to the synthesis and the
reactivity of tertiary phosphines, but excluding the chemistry of their metal complexes …