Abstract 2D NMR is extensively used in many different fields, and its potential for the study of
complex biochemical or chemical mixtures has been widely demonstrated. 2D NMR gives …

NMR spectroscopy is a versatile tool for studying time-dependent processes: chemical
reactions, phase transitions or macromolecular structure changes. However, time-resolved …

Mobility of reactants and nearby solvent is more rapid than Brownian diffusion during
several common chemical reactions when the energy release rate exceeds a threshold …

NMR spectroscopy is a powerful approach for the analysis of mixtures. Its usefulness arises
in large part from the vast landscape of methods, and corresponding pulse sequences, that …

Relaxation and diffusion NMR measurements offer an approach to studying rotational and
translational motion of molecules non-invasively, and they also provide chemical resolution …

Dihydrogen phosphate anions are found to spontaneously associate into anti-electrostatic
oligomers via hydrogen bonding interactions at millimolar concentrations in DMSO. Diffusion …

Micrometer-sized objects are widely known to exhibit chemically driven motility in systems
away from equilibrium. Experimental observation of reaction-induced motility or …

The reported changes in self-diffusion of small molecules during reactions have been
attributed to “boosted mobility”. We demonstrate the critical role of changing concentrations …

Online, high-throughput molecular weight analysis of polymerizations is rare, with most
studies relying on tedious sampling techniques and batchwise postanalysis. The ability to …

The apparent “boosted mobility” observed by Wang et al.(Reports, 31 July 2020, p. 537) is
the result of a known artifact. When signal intensities are changing during a nuclear …