Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Sulfoximines, sulfondiimides and sulfonimidamides are fascinating but not yet fully explored
variants of the common sulfone or sulfonamide motif. In this study, we report the …

Chiral sulfoximines have a stereogenic center at the sulfur atom and their use in asymmetric
synthesis is well established. Recently, sulfoximines have been recognized as an interesting …

The Rh (II)-catalyzed imination of sulfoxides and sulfides using [Rh2 (OAc) 4] as a catalyst
and trifluoroacetamide or sulfonylamides in combination with iodobenzene diacetate and …

We report a data-driven, physical organic approach to the development of new methionine-
selective bioconjugation reagents with tunable adduct stabilities. Statistical modeling of …

The synthesis of N-cyanosulfilimines can readily be achieved by reaction of the
corresponding sulfides with cyanogen amine in the presence of a base and NBS or I2 as …

Copper-mediated cross-coupling reactions of sulfoximines with aryl iodides and aryl
bromides provide N-arylated sulfoximines in high yields. The method is complementary to …

The Fe (III)-catalyzed imination of sulfoxides and sulfides with sulfonylamides in the
presence of iodinanes has been investigated. The best results were obtained when Fe …

Two simple and inexpensive systems for copper-catalyed N-arylations of sulfoximines with
aryl bromides and aryl iodides have been developed. Using 10 mol% of a copper (I) salt in …

A metal-free and operationally simple N-arylation of NH-sulfoximines with aryne precursors
is reported. Transition metal-free reaction conditions and shorter reaction times are the …