From a one-mode to a multi-mode understanding of conical intersection mediated ultrafast organic photochemical reactions
Y Boeije, M Olivucci - Chemical Society Reviews, 2023 - pubs.rsc.org
Over the last few decades, conical intersections (CoIns) have grown from theoretical
curiosities into common mechanistic features of photochemical reactions, whose function is …
curiosities into common mechanistic features of photochemical reactions, whose function is …
Revealing Excited‐State Trajectories on Potential Energy Surfaces with Atomic Resolution in Real Time
D Leshchev, A JS Valentine, P Kim… - Angewandte Chemie …, 2023 - Wiley Online Library
Photoexcited molecular trajectories on potential energy surfaces (PESs) prior to
thermalization are intimately connected to the photochemical reaction outcome. The excited …
thermalization are intimately connected to the photochemical reaction outcome. The excited …
Vibrational Coherence in the Metal–Metal-Bonded Excited State of Pt (II) Complexes
In the past decade, there have been significant advancements in the investigation of
coherence-related phenomena in organic systems such as biological photosynthetic …
coherence-related phenomena in organic systems such as biological photosynthetic …
Deciphering Charge Transfer Processes in Transition Metal Complexes from the Perspective of Ultrafast Electronic and Nuclear Motions
MW Mara, NP Weingartz, D Leshchev… - The Journal of …, 2024 - ACS Publications
Chemical transformations in charge transfer states result from the interplay between
electronic dynamics and nuclear reorganization along excited-state trajectories. Here, we …
electronic dynamics and nuclear reorganization along excited-state trajectories. Here, we …
Spin–vibronic mechanism at work in a luminescent square-planar cyclometalated tridentate Pt (ii) complex: absorption and ultrafast photophysics
The absorption spectrum of [Pt (dpybMe) Cl](dpyb= 2, 6-di-(2-pyridyl) benzene),
representative of luminescent halide-substituted tridentate cyclometalated square planar Pt …
representative of luminescent halide-substituted tridentate cyclometalated square planar Pt …
Polystyrene-based eosin-Y as a photocatalyst for solar light-mediated NADH/NADPH regeneration and organic transformations
The development of a highly efficient, polymer-based photocatalyst for the solar light-
mediated photocatalytic reaction is a key challenge in this era. In this study, we report an …
mediated photocatalytic reaction is a key challenge in this era. In this study, we report an …
Unveiling the double triplet nature of the 2Ag state in conjugated stilbenoid compounds to achieve efficient singlet fission
In this investigation, the excited-state evolution in a series of all-trans stilbenoid compounds,
displaying a low-lying dark singlet state of 2Ag-like symmetry nearly degenerate with the …
displaying a low-lying dark singlet state of 2Ag-like symmetry nearly degenerate with the …
Excited state processes of dinuclear Pt (II) complexes bridged by 8-hydroxyquinoline
Dinuclear d8 Pt (II) complexes, where two mononuclear square planar Pt (II) units are
bridged in an “A-frame” geometry, possess photophysical properties characterised by either …
bridged in an “A-frame” geometry, possess photophysical properties characterised by either …
Real-time capture of nuclear motions influencing photoinduced electron transfer
Although vibronic coupling phenomena have been recognized in the excite state dynamics
of transition metal complexes, its impact on photoinduced electron transfer (PET) remains …
of transition metal complexes, its impact on photoinduced electron transfer (PET) remains …
N,C,N-Pincers in Platinum Bimetallic Complexes: Influence of the Pincer and Bridging Ligands on the Metal–Metal Bond and the Photophysical Properties
MA Esteruelas, S Moreno-Blázquez, M Oliván… - Inorganic …, 2024 - ACS Publications
Precursors PtCl {κ3-N, C, N-[py-C6HMe2-py]}(1), PtCl {κ3-N, C, N-[py-O-C6H3-O-py]}(2), Pt
(OH){κ3-N, C, N-[py-C6HMe2-py]}(3), and Pt (OH){κ3-N, C, N-[py-O-C6H3-O-py]}(4) were …
(OH){κ3-N, C, N-[py-C6HMe2-py]}(3), and Pt (OH){κ3-N, C, N-[py-O-C6H3-O-py]}(4) were …