The Scholl reaction as a powerful tool for synthesis of curved polycyclic aromatics

Y Zhang, SH Pun, Q Miao - Chemical Reviews, 2022 - ACS Publications
The past decade has witnessed remarkable success in the synthesis of curved polycyclic
aromatics through Scholl reactions which enable oxidative aryl–aryl coupling even in …

Dual‐metal atom electrocatalysts: theory, synthesis, characterization, and applications

A Pedersen, J Barrio, A Li, R Jervis… - Advanced Energy …, 2022 - Wiley Online Library
Electrochemical clean energy conversion and the production of sustainable chemicals are
critical in the journey to realizing a truly sustainable society. To progress electrochemical …

Helical Synthetic Nanographenes with Atomic Precision

Y Zhu, J Wang - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Understanding and harnessing the properties of nanoscale molecular entities
are considered as new frontiers in basic chemistry. In this regard, synthetic nanographene …

In situ formation of polycyclic aromatic hydrocarbons as an artificial hybrid layer for lithium metal anodes

S Chang, X Jin, Q He, T Liu, J Fang, Z Shen, Z Li… - Nano Letters, 2021 - ACS Publications
Nonuniform Li deposition causes dendrites and low Coulombic efficiency (CE), seriously
hindering the practical applications of Li metal. Herein, we developed an artificial solid-state …

Helical nanographenes embedded with contiguous azulene units

N Ogawa, Y Yamaoka, H Takikawa… - Journal of the …, 2020 - ACS Publications
The azulene moiety, composed of contiguous pentagonal and heptagonal rings, is a
structural defect that alters the electronic, magnetic, and structural properties of graphenes …

Bowl‐Shaped Pentagon‐ and Heptagon‐Embedded Nanographene Containing a Central Pyrrolo[3,2‐b]pyrrole Core

M Krzeszewski, Ł Dobrzycki, AL Sobolewski… - Angewandte …, 2021 - Wiley Online Library
A bowl‐shaped nitrogen‐doped nanographene composed of a pyrrolo [3, 2‐b] pyrrole core
substituted with six arene rings circularly bonded with one another has been prepared via a …

Saddle-shaped aza-nanographene with multiple odd-membered rings

M Krzeszewski, Ł Dobrzycki, AL Sobolewski… - Chemical …, 2023 - pubs.rsc.org
A saddle-shaped aza-nanographene containing a central 1, 4-dihydropyrrolo [3, 2-b] pyrrole
(DHPP) has been prepared via a rationally designed four-step synthetic pathway …

Reactivity, Regioselectivity, and Synthetic Application of 2-Pyrenyl Units in Scholl Reactions

SH Pun, ECH Wen, Z Xia, H Chen, FR Fischer… - CCS …, 2023 - chinesechemsoc.org
We herein report the reactivity and regioselectivity of 2-pyrenyl as a coupling unit in Scholl
reactions. On the basis of the Scholl reactions of hexaarylbenzene substrates, we have …

Nanographene with multiple embedded heptagons: cascade radical photocyclization

ZL Qiu, XW Chen, YD Huang, RJ Wei… - Angewandte Chemie …, 2022 - Wiley Online Library
Although heptagons are widely found in graphenic materials, the precise synthesis of
nanocarbons containing heptagons remains a challenge, especially for the nanocarbons …

Exceeding the volcano relationship in oxygen reduction/evolution reactions using single-atom-based catalysts with dual-active-sites

X Li, S Duan, E Sharman, Y Zhao, L Yang… - Journal of Materials …, 2020 - pubs.rsc.org
Finding cost-effective catalysts to drive oxygen reduction/evolution reactions (ORR/OER) is a
highly attractive goal. Most catalysts follow a volcano relationship of performance, making it …