Gas-phase reactions of isoprene and its major oxidation products
Isoprene carries approximately half of the flux of non-methane volatile organic carbon
emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and …
emitted to the atmosphere by the biosphere. Accurate representation of its oxidation rate and …
Criegee intermediates and their impacts on the troposphere
Criegee intermediates (CIs), carbonyl oxides formed in ozonolysis of alkenes, play key roles
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
in the troposphere. The decomposition of CIs can be a significant source of OH to the …
Ubiquitous atmospheric production of organic acids mediated by cloud droplets
Atmospheric acidity is increasingly determined by carbon dioxide and organic acids,–.
Among the latter, formic acid facilitates the nucleation of cloud droplets and contributes to …
Among the latter, formic acid facilitates the nucleation of cloud droplets and contributes to …
Water Charge Transfer Accelerates Criegee Intermediate Reaction with H2O– Radical Anion at the Aqueous Interface
Criegee intermediates (CIs) are important carbonyl oxides that may react with atmospheric
trace chemicals and impact the global climate. The CI reaction with water has been widely …
trace chemicals and impact the global climate. The CI reaction with water has been widely …
Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII–Criegee intermediates
RA Cox, M Ammann, JN Crowley… - Atmospheric …, 2020 - acp.copernicus.org
This article, the seventh in the series, presents kinetic and photochemical data sheets
evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It …
evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It …
Four-carbon Criegee intermediate from isoprene ozonolysis: Methyl vinyl ketone oxide synthesis, infrared spectrum, and OH production
The reaction of ozone with isoprene, one of the most abundant volatile organic compounds
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …
in the atmosphere, produces three distinct carbonyl oxide species (RR′ COO) known as …
Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
Criegee intermediate reactions with carboxylic acids: A potential source of secondary organic aerosol in the atmosphere
R Chhantyal-Pun, B Rotavera… - ACS Earth and Space …, 2018 - ACS Publications
Trace atmospheric concentrations of carboxylic acids have a potent effect upon the
environment, where they modulate aqueous chemistry and perturb Earth's radiative balance …
environment, where they modulate aqueous chemistry and perturb Earth's radiative balance …
Unimolecular decay of Criegee intermediates to OH radical products: Prompt and thermal decay processes
MI Lester, SJ Klippenstein - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Alkene ozonolysis is a primary oxidation pathway for anthropogenic and
biogenic alkenes emitted into the troposphere. It is also an important source of atmospheric …
biogenic alkenes emitted into the troposphere. It is also an important source of atmospheric …
Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
Elucidating atmospheric oxidation mechanisms is necessary for estimating the lifetimes of
atmospheric species and understanding secondary organic aerosol formation and …
atmospheric species and understanding secondary organic aerosol formation and …