Revealing key structural features hidden in liquids and glasses

H Tanaka, H Tong, R Shi, J Russo - Nature Reviews Physics, 2019 - nature.com
A great success of solid state physics comes from the characterization of crystal structures in
the reciprocal (wave vector) space. The power of structural characterization in Fourier space …

Revealing the role of liquid preordering in crystallisation of supercooled liquids

YC Hu, H Tanaka - Nature communications, 2022 - nature.com
The recent discovery of non-classical crystal nucleation pathways has revealed the role of
fluctuations in the liquid structural order, not considered in classical nucleation theory. On …

[HTML][HTML] Liquid–liquid transition and polyamorphism

H Tanaka - The Journal of Chemical Physics, 2020 - pubs.aip.org
Two or more liquid states may exist even for single-component substances, which is known
as liquid polymorphism, and the transition between them is called liquid–liquid transition …

Molecular nucleation mechanisms and control strategies for crystal polymorph selection

AES Van Driessche, N Van Gerven, PHH Bomans… - Nature, 2018 - nature.com
The formation of condensed (compacted) protein phases is associated with a wide range of
human disorders, such as eye cataracts, amyotrophic lateral sclerosis, sickle cell anaemia …

Nonclassical nucleation pathways in protein crystallization

F Zhang - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
Classical nucleation theory (CNT), which was established about 90 years ago, has been
very successful in many research fields, and continues to be the most commonly used theory …

Designing solid materials from their solute state: a shift in paradigms toward a holistic approach in functional materials chemistry

D Gebauer, SE Wolf - Journal of the American Chemical Society, 2019 - ACS Publications
“Non-classical” notions consider formation pathways of crystalline materials where larger
species than monomeric chemical constituents, ie, ions or single molecules, play crucial …

Microscopic mechanisms of pressure-induced amorphous-amorphous transitions and crystallisation in silicon

Z Fan, H Tanaka - Nature Communications, 2024 - nature.com
Some low-coordination materials, including water, silica, and silicon, exhibit polyamorphism,
having multiple amorphous forms. However, the microscopic mechanism and kinetic …

Supercooled and glassy water: Metastable liquid (s), amorphous solid (s), and a no-man's land

PH Handle, T Loerting… - Proceedings of the …, 2017 - National Acad Sciences
We review the recent research on supercooled and glassy water, focusing on the possible
origins of its complex behavior. We stress the central role played by the strong directionality …

Fast crystal growth at ultra-low temperatures

Q Gao, J Ai, S Tang, M Li, Y Chen, J Huang, H Tong… - Nature Materials, 2021 - nature.com
It is believed that the slow liquid diffusion and geometric frustration brought by a rapid, deep
quench inhibit fast crystallization and promote vitrification. Here we report fast crystal growth …

The potential of chemical bonding to design crystallization and vitrification kinetics

C Persch, MJ Müller, A Yadav, J Pries, N Honné… - Nature …, 2021 - nature.com
Controlling a state of material between its crystalline and glassy phase has fostered many
real-world applications. Nevertheless, design rules for crystallization and vitrification kinetics …