Arynes and donor–acceptor (D–A) cyclopropanes are two classes of strained systems
having the potential for numerous applications in organic synthesis. The last two decades …

Conspectus Donor–acceptor (D–A) cyclopropanes have gained increased momentum over
the past two decades. The use of these highly strained three-membered entities paved the …

Electro‐organic synthesis has attracted a lot of attention in pharmaceutical science,
medicinal chemistry, and future industrial applications in energy storage and conversion. To …

Nitrogen‐containing molecules are the key structural constituent of many pharmaceutical
compounds that play a pivotal role in drug development. Owing to their multifaceted …

We describe the first electrochemical activation of D–A cyclopropanes and D–A
cyclobutanes leading after C (sp3)− C (sp3) cleavage to the formation of highly reactive …

Ring opening of donor–acceptor cyclopropanes with various N-nucleophiles provides a
simple approach to 1, 3-functionalized compounds that are useful building blocks in organic …

The first ring‐opening reaction of donor–acceptor cyclopropanes to give diamines is
reported. For this reaction, a 1, 3‐bisfunctionalization was developed using cyclopropanes …

Abstract The first (3+ 3)‐annulation process of donor–acceptor cyclopropanes using
synergistic catalysis is reported. The Rh2 (OAc) 4‐catalyzed decomposition of diazo …

Abstract The kinetics of (3+ 2) cycloaddition reactions of 18 different donor–acceptor
cyclopropanes with the same aldehyde were studied by in situ NMR spectroscopy …

An organocatalytic enantioselective (3+ 3)-cycloaddition reaction of racemic cyclopropane
carbaldehydes and aryl hydrazones has been demonstrated for the first time. A wide range …