Is ice nucleation by organic crystals nonclassical? An assessment of the monolayer hypothesis of ice nucleation

AK Metya, V Molinero - Journal of the American Chemical Society, 2021 - ACS Publications
Potent ice nucleating organic crystals display an increase in nucleation efficiency with
pressure and memory effect after pressurization that set them apart from inorganic …

Ice–Liquid oscillations in nanoconfined water

N Kastelowitz, V Molinero - ACS nano, 2018 - ACS Publications
Nanoscale confinement has a strong effect on the phase behavior of water. Studies in the
last two decades have revealed a wealth of novel crystalline and quasicrystalline structures …

[HTML][HTML] Microscopic ordering of supercooled water on the ice basal face

K Mochizuki, K Murata, X Zhang - Communications Materials, 2023 - nature.com
Growth of ice crystals is ubiquitous around us, but we still do not know what is occurring at
the forefront of crystallization. In general, the interfacial structure is inseparably involved in …

Ice nucleation in aqueous solutions of short-and long-chain poly (vinyl alcohol) studied with a droplet microfluidics setup

L Eickhoff, M Keßler, C Stubbs, J Derksen… - The Journal of …, 2023 - pubs.aip.org
Poly (vinyl alcohol)(PVA) has ice binding and ice nucleating properties. Here, we explore
the dependence of the molecular size of PVA on its ice nucleation activity. For this purpose …

What controls the limit of supercooling and superheating of pinned ice surfaces?

PM Naullage, Y Qiu, V Molinero - The journal of physical …, 2018 - ACS Publications
Cold-adapted organisms produce antifreeze proteins and glycoproteins to control the
growth, melting and recrystallization of ice. It has been proposed that these molecules pin …

Characterizing key features in the formation of ice and gas hydrate systems

S Liang, KW Hall, A Laaksonen… - … Transactions of the …, 2019 - royalsocietypublishing.org
Crystallization in liquids is critical to a range of important processes occurring in physics,
chemistry and life sciences. In this article, we review our efforts towards understanding the …

Understanding the role of polymers on the nucleating behavior of water in dilute supercooled solutions

A Indra, M Bhendale, JK Singh - The Journal of Chemical Physics, 2023 - pubs.aip.org
Understanding the nucleation behavior of water in dilute polymeric solutions is
quintessential for the development of suitable artificial ice recrystallization inhibition (IRI) …

Is water at the graphite interface vapor-like or ice-like?

Y Qiu, L Lupi, V Molinero - The Journal of Physical Chemistry B, 2018 - ACS Publications
Graphitic surfaces are the main component of soot, a major constituent of atmospheric
aerosols. Experiments indicate that soots of different origins display a wide range of abilities …

Ice Nucleation Promotion Impact on the Ice Recrystallization Inhibition Activity of Polyols

M Mousazadehkasin, N Mitchell… - …, 2023 - ACS Publications
Heterogeneous ice nucleation occurs vis-à-vis nucleating agents already present in solution
yet can occur within a rather broad range of temperatures (0 to ca.− 38° C). Controlling this …

Insights into design of biomimetic glycerol-grafted polyol-based polymers for ice nucleation/recrystallization inhibition and thermal hysteresis activity

M Mousazadehkasin, JG Tsavalas - Biomacromolecules, 2020 - ACS Publications
Many species living in colder regions of the world have adapted to the extreme climate by
producing antifreeze (glycol) proteins (AF (G) P) which exhibit ice recrystallization inhibition …