Stability of adsorbed polystyrene nanolayers on silicon substrates

N Jiang, JM Cheung, Y Guo, MK Endoh… - Macromolecular …, 2018 - Wiley Online Library
The solid–polymer melt interface is of great scientific interest due to its vital importance in
governing a wide array of physical and mechanical properties of polymer thin films. Recent …

Improvement of polymer adhesion by designing the interface layer

D Kawaguchi, R Nakayama, H Koga, M Totani… - polymer, 2023 - Elsevier
Polymer adhesion with inorganic materials is a key technology for realizing the
diversification of materials. When a polymer contacts with inorganic materials, a layer …

Local orientation of chains at crystal/amorphous interfaces buried in isotactic polypropylene thin films

D Kawaguchi, K Yamamoto, T Abe, N Jiang… - Physical Chemistry …, 2021 - pubs.rsc.org
A better understanding of the aggregation states of polymer chains in thin films is of pivotal
importance for developing thin film polymer devices in addition to its inherent scientific …

Interplay between free surface and solid interface nucleation on two-step crystallization of poly (ethylene terephthalate) thin films studied by fast scanning calorimetry

S Luo, X Kui, E Xing, X Wang, G Xue, C Schick… - …, 2018 - ACS Publications
Under confinement, unique features of crystallization arise, among which the slowing down
and accelerating crystallization on cooling are both reported. The controversy can be …

Interfacial irreversibly and loosely adsorbed layers abide by different evolution dynamics

X Li, X Lu - ACS Macro Letters, 2019 - ACS Publications
Within the interfacial region of the substrate, polymer chains can form the inner irreversibly
adsorbed and outer loosely adsorbed layers upon annealing. Owing to their different …

Effect of oligomer segregation on the aggregation state and strength at the polystyrene/substrate interface

M Inutsuka, H Watanabe, M Aoyagi… - ACS Macro …, 2022 - ACS Publications
The interfacial strength of polystyrene (PS) with and without PS oligomers in contact with a
glass substrate was examined to determine the relationship between the interfacial …

Chain conformation near the buried interface in nanoparticle-stabilized polymer thin films

DA Barkley, N Jiang, M Sen, MK Endoh… - …, 2017 - ACS Publications
It is known that when nanoparticles are added to polymer thin films, they often migrate to the
film–substrate interface and form an “immobile interfacial layer”, which is believed to be the …

[HTML][HTML] Growth kinetics of the adsorbed layer of poly (bisphenol A carbonate) and its effect on the glass transition behavior in thin films

H Omar, G Hidde, P Szymoniak, A Hertwig… - RSC …, 2023 - pubs.rsc.org
The glass transition behavior of thin films of poly (bisphenol A carbonate)(PBAC) was
studied employing ellipsometry. The glass transition temperature increases with the …

Comparing the impact of different adsorbed layers on the local glass transition of polymer matrices

MF Thees, JH Merrill, X Huang, CB Roth - The Journal of Chemical …, 2024 - pubs.aip.org
Chain adsorption to nanofiller interfaces creating bound layers has become central to
understanding property changes in polymer nanocomposites. We determine the impact …

Effects of polarity of polymers on conformation and lubricating film formation of adsorbed films

Y Song, K Fukuzawa, T Hirayama, N Yamashita… - …, 2023 - ACS Publications
The conformations and lubricating film formation ability of adsorbed films on metal surfaces
formed by poly (alkyl methacrylate)(PAMA) homopolymers with different polarities from …