Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds

B Liu, AM Romine, CZ Rubel, KM Engle… - Chemical reviews, 2021 - ACS Publications
Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …

The crucial role of silver (i)-salts as additives in C–H activation reactions: overall analysis of their versatility and applicability

RL de Carvalho, EBT Diogo, SL Homölle… - Chemical Society …, 2023 - pubs.rsc.org
Transition-metal catalyzed C–H activation reactions have been proven to be useful
methodologies for the assembly of synthetically meaningful molecules. This approach bears …

Transient imine directing groups for the C–H functionalisation of aldehydes, ketones and amines: an update 2018–2020

JI Higham, JA Bull - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
The use of pre-installed directing groups has become a popular and powerful strategy to
control site selectivity in transition metal catalysed C–H functionalisation reactions. However …

Mechanistic views and computational studies on transition-metal-catalyzed reductive coupling reactions

A Duan, F Xiao, Y Lan, L Niu - Chemical Society Reviews, 2022 - pubs.rsc.org
Transition-metal-catalyzed reductive coupling reactions have been considered as a
powerful tool to convert two electrophiles into value-added products. Numerous related …

Late-Stage β-C(sp3)–H Deuteration of Carboxylic Acids

A Uttry, S Mal, M van Gemmeren - Journal of the American …, 2021 - ACS Publications
Carboxylic acids are highly abundant in bioactive molecules. In this study, we describe the
late-stage β-C (sp3)–H deuteration of free carboxylic acids. On the basis of the finding that C …

PdII‐Catalyzed Enantioselective C(sp3)–H Arylation of Cyclobutyl Ketones Using a Chiral Transient Directing Group

LJ Xiao, K Hong, F Luo, L Hu, WR Ewing… - Angewandte Chemie …, 2020 - Wiley Online Library
The use of chiral transient directing groups (TDGs) is a promising approach for developing
PdII‐catalyzed enantioselective C (sp3)− H activation reactions. However, this strategy is …

Ligand-Enabled Pd(II)-Catalyzed β-Methylene C(sp3)–H Arylation of Free Aliphatic Acids

L Hu, G Meng, JQ Yu - Journal of the American Chemical Society, 2022 - ACS Publications
Ligand development has enabled rapid advances in Pd (II)-catalyzed β-methyl C (sp3)–H
activation of free carboxylic acids. However, there are only a handful of reports of free-acid …

Controlling carbon monoxide emissions from automobile vehicle exhaust using copper oxide catalysts in a catalytic converter

S Dey, GC Dhal - Materials Today Chemistry, 2020 - Elsevier
Carbon monoxide (CO) is a very poisonous gas present in the atmosphere. It has significant
effects on human beings, animals, plants and the climate. Automobile vehicle exhaust …

Palladium‐Catalyzed Site‐Selective [3+2] Annulation via Benzylic and meta C−H Bond Activation

Q He, N Chatani - Angewandte Chemie International Edition, 2021 - Wiley Online Library
Abstract The palladium‐catalyzed [3+ 2] annulation of aromatic amides with maleimides via
the activation of ortho benzylic C− H and meta C− H bonds is reported. Carboxamide and …

Site‐Selective C(sp3)−H and C(sp2)−H Functionalization of Amines Using a Directing‐Group‐Guided Strategy

M Kapoor, A Singh, K Sharma… - Advanced Synthesis & …, 2020 - Wiley Online Library
Amines represent an important class of industrial feedstock as many pharmaceuticals,
agrochemicals, petrochemicals, and healthcare products are derived from them …