Recent advances in the synthesis and applications of macrocyclic arenes

XN Han, Y Han, CF Chen - Chemical Society Reviews, 2023 - pubs.rsc.org
Macrocyclic arenes including calixarenes, resorcinarenes, cyclotriveratrylene, pillararenes
and so on have emerged as highly attractive synthetic macrocyclic hosts due to their unique …

Converting pH probes into “turn-on” fluorescent receptors for anions

EA Kataev - Chemical Communications, 2023 - pubs.rsc.org
Recognition of anions by synthetic receptors is an integral part of supramolecular chemistry
continuing to expand and find new application areas in our daily life. Many applications …

Conjugated Nanohoop Polymers based on Antiaromatic Dibenzopentalenes for Charge Storage in Organic Batteries

P Seitz, M Bhosale, L Rzesny, A Uhlmann… - Angewandte …, 2023 - Wiley Online Library
With their bent π‐systems, cyclic conjugation and inherent cavities, conjugated nanohoops
are attractive for organic electronics applications. For ease of processing and morphological …

The green box: Selenoviologen-based tetracationic cyclophane for electrochromism, host–guest interactions, and visible-light photocatalysis

Y Li, N Li, G Li, Y Qiao, M Zhang, L Zhang… - Journal of the …, 2023 - ACS Publications
The novel selenoviologen-based tetracationic cyclophanes (green boxes 3 and 5) with rigid
electron-deficient cavities are synthesized via SN2 reactions in two steps. The green boxes …

Thermally Controlled Exciplex Fluorescence in a Dynamic Homo [2] catenane

A Garci, AHG David, L Le Bras, M Ovalle… - Journal of the …, 2022 - ACS Publications
Motion-induced change in emission (MICE) is a phenomenon that can be employed to
develop various types of probes, including temperature and viscosity sensors. Although …

Exciplex Emission and Förster Resonance Energy Transfer in Polycyclic Aromatic Hydrocarbon-Based Bischromophoric Cyclophanes and Homo [2] catenanes

A Garci, S Abid, AHG David, LO Jones… - Journal of the …, 2023 - ACS Publications
Energy transfer and exciplex emission are not only crucial photophysical processes in many
living organisms but also important for the development of smart photonic materials. We …

Supramolecular photosensitizers using extended macrocyclic hosts for photodynamic therapy with distinct cellular delivery

X Zheng, SN Lei, Z Gao, X Dong, H Xiao, W Liu… - Chemical …, 2023 - pubs.rsc.org
The photosensitizers (PSs) for photodynamic therapy (PDT) mostly possess conjugated
skeletons that are over-sized and poorly water-soluble to be encapsulated by conventional …

Aggregation‐Induced Emission and Circularly Polarized Luminescence Duality in Tetracationic Binaphthyl‐Based Cyclophanes

A Garci, S Abid, AHG David, MD Codesal… - Angewandte …, 2022 - Wiley Online Library
Here, we report an approach to the synthesis of highly charged enantiopure cyclophanes by
the insertion of axially chiral enantiomeric binaphthyl fluorophores into the constitutions of …

Alkoxy-substituted quadrupolar fluorescent dyes

Y Feng, PJ Das, RM Young, PJ Brown… - Journal of the …, 2022 - ACS Publications
Polar and polarizable π-conjugated organic molecules containing push–pull chromophores
have been investigated extensively in the past. Identifying unique backbones and building …

Structure–property relationship of macrocycles in organic photoelectric devices: a comprehensive review

C Zhong, Y Yan, Q Peng, Z Zhang, T Wang, X Chen… - Nanomaterials, 2023 - mdpi.com
Macrocycles have attracted significant attention from academia due to their various
applications in organic field-effect transistors, organic light-emitting diodes, organic …