A novel ruthenium-catalyzed dehydrogenative synthesis of 2-arylquinazolines from 2-aminoaryl methanols and benzonitriles

M Chen, M Zhang, B Xiong, Z Tan, W Lv, H Jiang - Organic letters, 2014 - ACS Publications
By employing a commercially available Ru3 (CO) 12/Xantphos/t-BuOK catalyst system, a
novel and straightforward ruthenium-catalyzed dehydrogenative synthesis of 2 …

Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia

J Luo, QQ Zhou, M Montag, Y Ben-David… - Chemical Science, 2022 - pubs.rsc.org
The highly desirable synthesis of the widely-used primary amides directly from alcohols and
ammonia via acceptorless dehydrogenative coupling represents a clean, atom-economical …

The Milstein bipyridyl PNN pincer complex of ruthenium becomes a Noyori-type catalyst under reducing conditions

LN Dawe, M Karimzadeh-Younjali, Z Dai… - Journal of the …, 2020 - ACS Publications
Hydrogenation of the dearomatized PNN ligand of the Milstein bipyridyl complex RuH
(CO)[PNN](2) gives a square-pyramidal Ru (II) product RuH (CO)[pPNN](5). The central ring …

Near-ambient-temperature dehydrogenative synthesis of the amide bond: mechanistic insight and applications

S Kar, Y Xie, QQ Zhou, Y Diskin-Posner… - ACS …, 2021 - ACS Publications
The current existing methods for the amide bond synthesis via acceptorless
dehydrogenative coupling of amines and alcohols all require high reaction temperatures for …

Iron-catalyzed amide formation from the dehydrogenative coupling of alcohols and secondary amines

EM Lane, KB Uttley, N Hazari, W Bernskoetter - Organometallics, 2017 - ACS Publications
The five-coordinate iron (II) hydride complex (i PrPNP) Fe (H)(CO)(i PrPNP= N [CH2CH2 (P i
Pr2)] 2) selectively catalyzes the dehydrogenative intermolecular coupling of alcohols and …

CO Oxidation by N2O Homogeneously Catalyzed by Ruthenium Hydride Pincer Complexes Indicating a New Mechanism

R Zeng, M Feller, Y Diskin-Posner… - Journal of the …, 2018 - ACS Publications
Both CO and N2O are important, environmentally harmful industrial gases. The reaction of
CO and N2O to produce CO2 and N2 has stimulated much research interest aimed at …

BODIPY catalyzed amide synthesis promoted by BHT and air under visible light

XF Wang, SS Yu, C Wang, D Xue, J Xiao - Organic & Biomolecular …, 2016 - pubs.rsc.org
A novel and efficient protocol for the synthesis of amides is reported which employs a
BODIPY catalyzed oxidative amidation reaction between aromatic aldehydes and amines …

General Synthesis of Amino Acid Salts from Amino Alcohols and Basic Water Liberating H2

P Hu, Y Ben-David, D Milstein - Journal of the American Chemical …, 2016 - ACS Publications
An atom-economical and environmentally friendly method to transform amino alcohols to
amino acid salts using just basic water, without the need of pre-protection or added oxidant …

Transition‐metal‐catalyzed dehydrogenative coupling of alcohols and amines: A novel and atom‐economical access to amides

MRP Heravi, A Hosseinian, Z Rahmani… - Journal of the …, 2021 - Wiley Online Library
The catalytic synthesis of amides directly from primary alcohols and amines represents an
atom‐economical and environmentally benign methodology, which produces H2 as the sole …

Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines

NJ Oldenhuis, VM Dong, Z Guan - Tetrahedron, 2014 - Elsevier
A commercially available ruthenium (II) PNP type pincer catalyst (Ru-Macho) promotes
formation of amides and imines from alcohols and amines via an acceptorless …