Proton transfer reactions involving transition metal hydride complexes are prevalent in a
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …

Abstract When Ziegler and Korav serendipitously prepared [Fe 2 (CO) 6 (μ-pdt)] in 1979 they
could not have anticipated that some 40 years later it would be a mainstay of attempts to …

The electronic structure of metal complexes plays key roles in determining their catalytic
features. However, controlling electronic structures to regulate reaction mechanisms is of …

Catalysis enables many aspects of modern life, including fuels, products, plastics, and
medicines. Recent advances in catalysis have enabled us to realize higher efficiencies and …

Rhenium-based metallodrugs have recently been highlighted as promising candidates for
new antibiotics to combat multi-drug resistant (MDR) pathogens. A new class of rhenium (V) …

The development of catalysts that can convert carbon dioxide (CO2) to useful reduced
products is a pressing and ongoing challenge. Refinement of the designs of molecular …

Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Hydrogen (H2) can be produced in the water splitting reaction, specifically on the cathodic
side through the hydrogen evolution reaction (HER), where two protons and two electrons …

We report an intermolecular Ni-catalyzed reductive coupling of aryl iodides and isatins to
form 3-hydroxyoxindoles. In contrast to common metal-mediated methods, sec-butanol is …

The extraordinary potential of hydrogen as a clean and sustainable fuel has sparked the
interest of the scientific community to find environmentally friendly methods for its production …