Proton transfer kinetics of transition metal hydride complexes and implications for fuel-forming reactions
CL Montgomery, J Amtawong, AM Jordan… - Chemical Society …, 2023 - pubs.rsc.org
Proton transfer reactions involving transition metal hydride complexes are prevalent in a
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …
number of catalytic fuel-forming reactions, where the proton transfer kinetics to or from the …
[HTML][HTML] An unexpected leading role for [Fe2 (CO) 6 (μ-pdt)] in our understanding of [FeFe]-H2ases and the search for clean hydrogen production
G Hogarth - Coordination Chemistry Reviews, 2023 - Elsevier
Abstract When Ziegler and Korav serendipitously prepared [Fe 2 (CO) 6 (μ-pdt)] in 1979 they
could not have anticipated that some 40 years later it would be a mainstay of attempts to …
could not have anticipated that some 40 years later it would be a mainstay of attempts to …
Switching Electrocatalytic Hydrogen Evolution Pathways through Electronic Tuning of Copper Porphyrins
X Peng, M Zhang, H Qin, J Han, Y Xu… - Angewandte Chemie …, 2024 - Wiley Online Library
The electronic structure of metal complexes plays key roles in determining their catalytic
features. However, controlling electronic structures to regulate reaction mechanisms is of …
features. However, controlling electronic structures to regulate reaction mechanisms is of …
Bioinspired Catalyst Design Principles: Progress in Emulating Properties of Enzymes in Synthetic Catalysts
Catalysis enables many aspects of modern life, including fuels, products, plastics, and
medicines. Recent advances in catalysis have enabled us to realize higher efficiencies and …
medicines. Recent advances in catalysis have enabled us to realize higher efficiencies and …
Synthesis and anti-microbial activity of a new series of bis (diphosphine) rhenium (v) dioxo complexes
Rhenium-based metallodrugs have recently been highlighted as promising candidates for
new antibiotics to combat multi-drug resistant (MDR) pathogens. A new class of rhenium (V) …
new antibiotics to combat multi-drug resistant (MDR) pathogens. A new class of rhenium (V) …
The Pattern of Hydroxyphenyl-Substitution Influences CO2 Reduction More Strongly than the Number of Hydroxyphenyl Groups in Iron-Porphyrin Electrocatalysts
The development of catalysts that can convert carbon dioxide (CO2) to useful reduced
products is a pressing and ongoing challenge. Refinement of the designs of molecular …
products is a pressing and ongoing challenge. Refinement of the designs of molecular …
Coordination-driven electrocatalysts as an evolving wave of enthusiasm for sustainable hydrogen production
Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …
fuel alternatives. Commercial-scale hydrogen production through water-splitting …
Covalent Attachment of Cobalt Bis (Benzylaminedithiolate) to Reduced Graphene Oxide as a Thin-Film Electrocatalyst for Hydrogen Production with Remarkable …
Hydrogen (H2) can be produced in the water splitting reaction, specifically on the cathodic
side through the hydrogen evolution reaction (HER), where two protons and two electrons …
side through the hydrogen evolution reaction (HER), where two protons and two electrons …
Reductive 1, 2-arylation of isatins
A Nasim, GT Thomas, JS Ovens, SG Newman - Organic Letters, 2022 - ACS Publications
We report an intermolecular Ni-catalyzed reductive coupling of aryl iodides and isatins to
form 3-hydroxyoxindoles. In contrast to common metal-mediated methods, sec-butanol is …
form 3-hydroxyoxindoles. In contrast to common metal-mediated methods, sec-butanol is …
Enzymatic and bioinspired systems for hydrogen production
The extraordinary potential of hydrogen as a clean and sustainable fuel has sparked the
interest of the scientific community to find environmentally friendly methods for its production …
interest of the scientific community to find environmentally friendly methods for its production …