Green solvents in carbohydrate chemistry: from raw materials to fine chemicals

A Farrán, C Cai, M Sandoval, Y Xu, J Liu… - Chemical …, 2015 - ACS Publications
In recent decades, there has been an increasing effort to reduce the use of fossil fuels and
oil derivatives, to decrease environmental pollution, and to counteract global warming. The …

Metal-catalyzed organic reactions using mechanochemistry

JG Hernández, T Friščić - Tetrahedron Letters, 2015 - Elsevier
The past decade has witnessed an explosive growth of interest in mechanochemical
reactions by milling or grinding, and rapid expansion of mechanochemical methodologies …

Mechanochemical Iridium (III)‐Catalyzed C− H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent‐Free Conditions in a Ball Mill

GN Hermann, P Becker, C Bolm - Angewandte Chemie, 2016 - Wiley Online Library
Mechanochemical conditions have been applied to an iridium (III)‐catalyzed C− H bond
amidation process for the first time. In the absence of solvent, the mechanochemical …

Mechanochemical ruthenium-catalyzed olefin metathesis

JL Do, C Mottillo, D Tan, V Strukil… - Journal of the American …, 2015 - ACS Publications
We describe the development of a mechanochemical approach for Ru-catalyzed olefin
metathesis, including cross-metathesis and ring-closing metathesis. The method uses …

Mechanochemical rhodium (III)-catalyzed C–H bond amidation of arenes with dioxazolones under solventless conditions in a ball mill

GN Hermann, C Bolm - ACS Catalysis, 2017 - ACS Publications
A procedure for the direct mechanochemical rhodium (III)-catalyzed C–H bond amidation of
arenes with 1, 4, 2-dioxazol-5-ones as the nitrogen source has been developed. The …

Mechanochemical Rhodium (III)‐Catalyzed C H Bond Functionalization of Acetanilides under Solventless Conditions in a Ball Mill

GN Hermann, P Becker, C Bolm - Angewandte Chemie, 2015 - Wiley Online Library
In a proof‐of‐principle study, a planetary ball mill was applied to rhodium (III)‐catalyzed C
H bond functionalization. Under solventless conditions and in the presence of a minute …

Current challenges and future perspectives in sustainable mechanochemical transformations of carbohydrates

A Perona, P Hoyos, Á Farrán, MJ Hernáiz - Green Chemistry, 2020 - pubs.rsc.org
The use of mechanochemistry in carbohydrate chemistry is currently a growing field in which
many new developments are being made because of its potential application in green …

Mechanochemical Rhodium (III)‐and Gold (I)‐Catalyzed C− H Bond Alkynylations of Indoles under Solventless Conditions in Mixer Mills

GN Hermann, MT Unruh, SH Jung… - Angewandte …, 2018 - Wiley Online Library
Mechanochemical activations in RhIII‐and AuI‐catalyzed C− H alkynylations lead selectively
to C2‐and C3‐alkynylated indoles. The processes show excellent functional group …

Mechanochemical indole synthesis by rhodium-catalysed oxidative coupling of acetanilides and alkynes under solventless conditions in a ball mill

GN Hermann, CL Jung, C Bolm - Green Chemistry, 2017 - pubs.rsc.org
A mechanochemical indole synthesis by rhodium (III)-catalysed C–H bond functionalisation
in a planetary mill has been developed. It occurs in the absence of any solvent, does not …

An Inexpensive and Recyclable Silver‐Foil Catalyst for the Cyclopropanation of Alkenes with Diazoacetates under Mechanochemical Conditions

L Chen, MO Bovee, BE Lemma… - Angewandte …, 2015 - Wiley Online Library
The diastereoselective cyclopropanation of various alkenes with diazoacetate derivatives
can be achieved under mechanochemical conditions using metallic silver foil and a …