Based on a β-diketiminate ligand, an iron (III) tetrahedral high-spin complex,[LFeIII (Cl) 2](1),
and an iron (II) high-spin triangular planar complex,[LFeIICl](2), have been synthesized and …

A family of isomorphous three‐dimensional metal–organic frameworks based on bimetallic
(FeCo, FeNi, and CoNi) chains with random metal sites have been prepared and …

Heavy 5d elements, like osmium, feature strong spin‐orbit interactions which are at the
origin of exotic physical behaviors. Revealing the full potential of, for example, novel osmium …

The perturbation to the ligand field around the lanthanide ion may significantly contribute to
the magnetic dynamics of single molecule magnets. This can be demonstrated by two typical …

A new highly anisotropic coordination heterobimetallic polymer [MnIII (Schiff-base)] 3 [ReIV
(CN) 7] was synthesized and characterized structurally and magnetically. The single crystal …

The single transition ions in various crystals or molecules as well as the exchange coupled
systems (ECS) of transition ions, especially the single molecule magnets (SMM) or …

We herein present the synthesis and magneto-structural study of a new family of
heterobimetallic chains of general formula {[FeIII (dmbpy)(CN) 4] 2MII (H2O) 2} n· pnH2O …

A series of isomorphous compounds of general formula [Co1–x Ni x (tzpo)(N3)(H2O) 2] n· n
H2O (x= 0, 0.19, 0.38, 0.53, 0.68, 0.84, and 1; tzpo= 4-(5-tetrazolate) pyridine-N-oxide) was …

The novel Re (II) complex NBu4 [Re (NO) Br4 (Hnic)](1) and the heterodinuclear compounds
[Re (NO) Br4 (μ-nic) Ni (dmphen) 2]· ½CH3CN (2),[Re (NO) Br4 (μ-nic) Co (dmphen) 2] …

Two novel ReIV salts of general formula [H2ade] 2 [ReIVX6] X2· 4H2O [H2ade2+= 9 H-
adenine-1, 7-diium; X= Cl (1) and Br (2)] have been synthesized and magnetostructurally …