Heterocyclic chemistry is an ever-expanding field without boundaries. Heterocycles play a
significant role in medicinal and pharmaceutical chemistry, the agricultural industry and …

Catalytic asymmetric dynamic kinetic resolution of configurationally labile bridged biaryls is
emerging as a powerful strategy for atropisomer synthesis. However, the reported examples …

Transition metal-controlled divergent annulation reactions of azomethine imines with
iodonium ylides via C-centered [1, 2]-rearrangement have been developed. The azomethine …

Herein, we report an unprecedented strategy for the simultaneous construction of a remote
C–N stereogenic axis and three contiguous stereogenic carbon centers via silver-catalyzed …

The mini‐review is focused on application of silver and its compounds in fluoroorganic
synthesis, and it reflects immense progress in this field which took place during the last two …

We describe herein an intriguing method for the synthesis of biaryl aldehydes bearing both
axial and central chirality through a desymmetric [3+ 2] cycloaddition reaction of activated …

The development of efficient processes for the preparation of structurally diverse axially
chiral biaryls has been an important goal in synthetic organic chemistry and asymmetric …

Magnesium (II)-catalyzed cascade reactions of N, N′-cyclic azomethine imines with indolyl-
substituted isocyanides are reported herein. The method exhibited a high functional group …

Abstract A diastereoselective (3+ 3) cycloaddition of azomethine imines and in situ‐
generated azaoxyallyl cations from α‐halohydroxamate promoted by a Brønsted base has …

Azomethine imines, as a prominent class of 1, 3‐dipolar species, hold great significance and
potential in organic and medicinal chemistry. However, the reported synthesis of centrally …