Shining new light on multifunctional lanthanide single‐molecule magnets
Single‐molecule magnets (SMMs) are at the forefront of new technological advances in
quantum information processing and spintronics. Despite the recent impressive …
quantum information processing and spintronics. Despite the recent impressive …
Synthesis and magnetism of neutral, linear metallocene complexes of terbium (II) and dysprosium (II)
The divalent metallocene complexes Ln (CpiPr5) 2 (Ln= Tb, Dy) were synthesized through
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …
The role of anharmonic phonons in under-barrier spin relaxation of single molecule magnets
The use of single molecule magnets in mainstream electronics requires their magnetic
moment to be stable over long times. One can achieve such a goal by designing compounds …
moment to be stable over long times. One can achieve such a goal by designing compounds …
Two-coordinate Co (II) imido complexes as outstanding single-molecule magnets
The pursuit of single-molecule magnets (SMMs) with better performance urges new
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …
Molecular approach to engineer two-dimensional devices for CMOS and beyond-CMOS applications
Two-dimensional materials (2DMs) have attracted tremendous research interest over the
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …
last two decades. Their unique optical, electronic, thermal, and mechanical properties make …
Single ion magnets from 3d to 5f: developments and strategies
M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
Understanding the magnetic anisotropy toward single-ion magnets
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …
preferentially after removal of the magnetic field below a certain temperature. The unique …
Strategies toward high-temperature lanthanide-based single-molecule magnets
L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …
magnetization blocking at the level of one molecule. In this paper, we examine the physical …
Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies
Incorporation of two characters into one molecular entity is an effective way to afford
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …
Spin crossover with thermal hysteresis: practicalities and lessons learnt
S Brooker - Chemical Society Reviews, 2015 - pubs.rsc.org
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …