When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F Jin - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Large magnetic anisotropy in mononuclear metal complexes

S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

Uncommon lanthanide ions in purely 4f Single Molecule Magnets

F Pointillart, O Cador, B Le Guennic… - Coordination Chemistry …, 2017 - Elsevier
Since the 1990s and the discovery of the first Single Molecule Magnets (SMMs), chemists
and physicists have been working in concert to elaborate such molecular systems and …

A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior

VV Novikov, AA Pavlov, YV Nelyubina… - Journal of the …, 2015 - ACS Publications
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …

Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

[HTML][HTML] A monometallic lanthanide bis (methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour

M Gregson, NF Chilton, AM Ariciu, F Tuna… - Chemical …, 2016 - pubs.rsc.org
We report a dysprosium (III) bis (methanediide) single molecule magnet (SMM) where
stabilisation of the highly magnetic states and suppression of mixing of opposite magnetic …

Switching the magnetic hysteresis of an [Feii–NC–Wv]-based coordination polymer by photoinduced reversible spin crossover

L Zhao, YS Meng, Q Liu, O Sato, Q Shi, H Oshio… - Nature Chemistry, 2021 - nature.com
Magnetic bistable materials that feature magnetic hysteresis are comparable to elementary
binary units and promising for application in switches and memory devices. In this work, we …

Fine‐tuning the local symmetry to attain record blocking temperature and magnetic remanence in a single‐ion magnet

L Ungur, JJ Le Roy, I Korobkov… - Angewandte …, 2014 - Wiley Online Library
Remanence and coercivity are the basic characteristics of permanent magnets. They are
also tightly correlated with the existence of long relaxation times of magnetization in a …

Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants

JL Liu, YC Chen, FS Guo, ML Tong - Coordination Chemistry Reviews, 2014 - Elsevier
This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry

JP Sutter, V Béreau, V Jubault, K Bretosh… - Chemical Society …, 2022 - pubs.rsc.org
The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …