When metal clusters meet carbon cages: endohedral clusterfullerenes
S Yang, T Wei, F Jin - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …
Large magnetic anisotropy in mononuclear metal complexes
S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …
theoretical approaches used to rationalize their magnetic properties. Electronic structure …
Uncommon lanthanide ions in purely 4f Single Molecule Magnets
F Pointillart, O Cador, B Le Guennic… - Coordination Chemistry …, 2017 - Elsevier
Since the 1990s and the discovery of the first Single Molecule Magnets (SMMs), chemists
and physicists have been working in concert to elaborate such molecular systems and …
and physicists have been working in concert to elaborate such molecular systems and …
A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
Main group chemistry at the interface with molecular magnetism
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …
heart of advances in molecular magnetism. Smart ligand design is essential for …
[HTML][HTML] A monometallic lanthanide bis (methanediide) single molecule magnet with a large energy barrier and complex spin relaxation behaviour
M Gregson, NF Chilton, AM Ariciu, F Tuna… - Chemical …, 2016 - pubs.rsc.org
We report a dysprosium (III) bis (methanediide) single molecule magnet (SMM) where
stabilisation of the highly magnetic states and suppression of mixing of opposite magnetic …
stabilisation of the highly magnetic states and suppression of mixing of opposite magnetic …
Switching the magnetic hysteresis of an [Feii–NC–Wv]-based coordination polymer by photoinduced reversible spin crossover
Magnetic bistable materials that feature magnetic hysteresis are comparable to elementary
binary units and promising for application in switches and memory devices. In this work, we …
binary units and promising for application in switches and memory devices. In this work, we …
Fine‐tuning the local symmetry to attain record blocking temperature and magnetic remanence in a single‐ion magnet
Remanence and coercivity are the basic characteristics of permanent magnets. They are
also tightly correlated with the existence of long relaxation times of magnetization in a …
also tightly correlated with the existence of long relaxation times of magnetization in a …
Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants
This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …
Magnetic anisotropy of transition metal and lanthanide ions in pentagonal bipyramidal geometry
The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …
sphere is examined on the basis of experimental and theoretical investigations. The origin …